Geopolymer binder is expected to be an optimum alternative to Portland cement due to its excellent engineering properties of high strength, acid corrosion resistance, low permeability, good chemical resistance, and excellent fire resistance. To study the sulfuric acid corrosion resistance of geopolymer concrete (GPC) with different binding materials and concentrations of sodium hydroxide solution (NaOH), metakaolin, high-calcium fly ash, and low-calcium fly ash were chosen as binding materials of GPC for the geopolymerization process. A mixture of sodium silicate solution (Na₂SiO₃) and NaOH solution with different concentrations (8 M and 12 M) was selected as the alkaline activator with a ratio (Na₂SiO₃/NaOH) of 1.5. GPC specimens were immersed in the sulfuric acid solution with the pH value of 1 for 6 days and then naturally dried for 1 day until 98 days. The macroscopic properties of GPC were characterized by visual appearance, compressive strength, mass loss, and neutralization depth. The materials were characterized by SEM, XRD, and FTIR. The results indicated that at the immersion time of 28 d, the compressive strength of two types of fly ash-based GPC increased to some extent due to the presence of gypsum, but this phenomenon was not observed in metakaolin-based GPC. After 98 d of immersion, the residual strength of fly ash based GPC was still higher, which reached more than 25 MPa, while the metakaolin-based GPC failed. Furthermore, due to the rigid 3D networks of aluminosilicate in fly ash-based GPC, the mass of all GPC decreased slightly during the immersion period, and then tended to be stable in the later period. On the contrary, in metakaolin-based GPC, the incomplete geopolymerization led to the compressive strength being too low to meet the application of practical engineering. In addition, the compressive strength of GPC activated by 12 M NaOH was higher than the GPC activated by 8 M NaOH, which is owing to the formation of gel depended on the concentration of alkali OH ion, low NaOH concentration weakened chemical reaction, and reduced compressive strength. Additionally, according to the testing results of neutralization depth, the neutralization depth of high-calcium fly ash-based GPC activated by 12 M NaOH suffered acid attack for 98 d was only 6.9 mm, which is the minimum value. Therefore, the best performance was observed in GPC prepared with high-calcium fly ash and 12 M NaOH solution, which is attributed to gypsum crystals that block the pores of the specimen and improve the microstructure of GPC, inhibiting further corrosion of sulfuric acid.

The global construction industry is increasingly utilizing concrete prepared from recycled aggregate as a substitute for natural aggregate. However, the subpar performance of recycled fine aggregate (RFA) has resulted in its underutilization, particularly in the structural concrete exposed to challenging environments, including those involving chlorine salts and freeze–thaw climates. This study aimed to enhance the performance of RFA as a substitute for river sand in concrete as well as fulfill the present demand for fine aggregates in the construction sector by utilizing accelerated carbonation treatment to create fully recycled aggregate concrete (FRAC) composed of 100% recycled coarse and fine aggregates. The impacts of incorporating carbonated recycled fine aggregate (C-RFA) at various replacement rates (0%, 25%, 50%, 75%, and 100%) on the mechanical and durability properties of FRAC were investigated. The results showed that the physical properties of C-RFA, including apparent density, water absorption, and crushing value, were enhanced compared to that of RFA. The compressive strength of C-RFC100 was 19.8% higher than that of C-RFC0, while the water absorption decreased by 14.6%. In a comparison of C-RFC0 and C-RFC100, the chloride permeability coefficients showed a 50% decrease, and the frost resistance increased by 27.6%. According to the findings, the mechanical and durability properties, the interfacial transition zones (ITZs), and micro-cracks of the C-RFC were considerably enhanced with an increased C-RFA content.

The use of conductive concrete is an effective way to address snow and ice accretion on roads in cold regions because of its energy saving and high efficiency without interruption of traffic. Composite conductive concrete was prepared using graphene, carbon fiber, and steel fiber, and the optimum dosage of graphene was explored with resistivity as the criterion. Subsequently, under the conditions of an initial temperature of −15 °C and a wind speed of 20 km/h, the extremely severe snow event environment in cold regions was simulated. The effects of electrode spacing and electric voltage on snow melting performance of conductive concrete slab were explored. Results showed that graphene can significantly improve the conductivity of conductive concrete; the optimal content of graphene was 0.4% of cement mass in terms of resistivity. The snow-melting power of conductive concrete slab decreased with increase in electrode spacing and increased with increase in on-voltage. For an optimal input voltage of 156 V and an optimal electrode spacing of 10 cm, the time required to melt a 24 h snow thickness (21 cm), accumulated during a simulated severe snow event, was only 2 h, which provides an empirical basis for the application of graphene composite conductive concrete to pavement snow melting in cold regions.