Hydrogen is a clean fuel and an abundant renewable energy resource. In recent years, huge scientific attention has been invested to invent suitable materials for its safe storage. Conducting polymers has been extensively investigated as a potential hydrogen storage and fuel cell membrane due to the low cost, ease of synthesis and processability to achieve the desired morphological and microstructural architecture, ease of doping and composite formation, chemical stability and functional properties. The review presents the recent progress in the direction of material selection, modification to achieve appropriate morphology and adsorbent properties, chemical and thermal stabilities. Polyaniline is the most explored material for hydrogen storage. Polypyrrole and polythiophene has also been explored to some extent. Activated carbons derived from conducting polymers have shown the highest specific surface area and significant storage. This review also covers recent advances in the field of proton conducting solid polymer electrolyte membranes in fuel cells application. This review focuses on the basic structure, synthesis and working mechanisms of the polymer materials and critically discusses their relative merits.
Citrus is the largest grown fruit crop on the globe with an annual production of ~110–124 million tons. Approximately, 45–55% of the whole fruit post-processing is generally discarded as waste by the food processing industries. The waste is a huge problem to the environment in terms of land and water pollution along with displeasure from aesthetic viewpoint and spread of diseases owing to its huge content of fermentable sugars. The waste can be utilized as a raw material feedstock for producing a number of valuable chemicals and products, such as bioethanol, biogas, bio-oil, organic acids, enzymes, and so on. The production of these chemicals from waste biomass gives an inexpensive alternative to the harsh chemicals used during industrial synthesis processes as well as the possibility of controlling pollution from the waste discarded to the environment. The derived chemicals can be further utilized in the production of industrially important chemicals, as solvents and building blocks of newer chemicals. Furthermore, organic acids, pectin, enzymes, prebiotics, etc., derived from citrus wastes have an edge over their synthetic counterparts in practical applications in the food processing and pharmaceutical industries.