The preparation of ultra-thin semi-transparent solar cells with potential applications in windows or transparent roofs entails several challenges due to the very small thickness of the layers involved. In particular, problems related to undesired inter-diffusion or inhomogeneities originated by incomplete coverage of the growing surfaces must be prevented. In this paper, undoped SnO₂, CdS, and CdTe thin films with thickness suitable for use in ultra-thin solar cells were deposited with a radiofrequency (RF) magnetron sputtering technique onto conductive glass. Preparation conditions were found for depositing the individual layers with good surface coverage, absence of pin holes and with a relatively small growth rate adapted for the control of very small thickness. After a careful growth calibration procedure, heterostructured solar cells devices were fabricated. The influence of an additional undoped SnO₂ buffer layer deposited between the conductive glass and the CdS window was studied. The incorporation of this layer led to an enhancement of both short circuit current and open circuit voltage (by 19 and 32%, respectively) without appreciable changes of other parameters. After the analysis of the cell parameters extracted from the current-voltage (I-V) curves, possible origins of these effects were found to be: Passivation effects of the SnO₂/CdS interface, blocking of impurities diffusion or improvement of the band alignment.

This study evaluates naproxen (NP) degradation efficiency by ozonation using nickel oxide films ($Ni{O}_{\left(F\right)}$) as a catalyst. The NiO films were synthesized by chemical vapor deposition and characterized by X-ray diffraction, scanning electron microscopy, atomic force microscopy and X-ray photoelectron spectroscopy. NP degradation was conducted for 5 min using 10 films of $Ni{O}_{\left(F\right)}$ comparing against ozonation using 100 mg/L $NiO$ powder in suspension ($Ni{O}_{\left(S\right)}$) and conventional ozonation ($O_3$-conv). Total organic carbon analysis demonstrated a mineralization degree of 12% with $O_3$-conv, 35% with $NiO$ as powder and 22% with $Ni{O}_{\left(F\right)}$ after 60 min of reaction. The films of $Ni{O}_{\left(F\right)}$ were sequentially used 4 times in ozonation demonstrating the stability of the synthesized material, as well as its properties as a catalyst for ozonation. A proposed modeling strategy using robust parametric identification techniques allows the comparison of NP decomposition pseudo-monomolecular reaction rates.

In this study, tomato plants were grown in vitro with and without incorporation of TiO₂ nanoparticles in Murashige and Skoog (MS) growth medium. The aim of this study was to describe the morphological (area and roundness cell) and mechanical (Young’s Modulus) change in the different tissue of tomato root, epidermis (Ep), parenchyma (Pa), and vascular bundles (Vb), when the whole plant was exposed to TiO₂ nanoparticles (TiO₂ NPs). light microscopy (LM), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and atomic force microscopy (AFM), wavelength dispersive X-ray fluorescence (WDXRF) techniques were used to identify changes into the root cells when TiO₂ NPs were incorporated. TiO₂ NPs incorporation produces changes in the area, roundness, and Young’s Modulus of the tomato root. When tomato root is exposed to TiO₂ NPs, the Ep and Vb area size decreases from 260.92 µm² to 160.71 µm² and, 103.08 µm² to 52.13 µm², respectively, compared with the control area, while in Pa tissue the area size was increased considerably from 337.72 mm² to 892.96 mm². Cellular roundness was evident in tomato root that was exposed to TiO₂ NPs in the Ep (0.49 to 0.67), Pa (0.63 to 0.79), and Vb (0.76 to 0.71) area zones. Young’s Modulus in Pa zone showed a rigid mechanical behavior when tomato root is exposed to TiO₂ NPs (0.48 to 4.98 MPa control and TiO₂ NPs, respectively). Meanwhile, Ep and Vb were softer than the control sample (13.9 to 1.06 MPa and 6.37 to 4.41 MPa respectively). This means that the Pa zone was stiffer than Ep and Vb when the root is exposed to TiO₂ NPs. Furthermore, TiO₂ NPs were internalized in the root tissue of tomato, accumulating mainly in the cell wall and intercellular spaces, with a wide distribution throughout the tissue, as seen in TEM.