Upconversion (UC) of lanthanide-doped nanostructure has the unique ability to convert low energy infrared (IR) light to high energy photons, which has significant potential for energy conversion applications. This review concisely discusses the basic concepts and fundamental theories of lanthanide nanostructures, synthesis techniques, and enhancement methods of upconversion for photovoltaic and for near-infrared (NIR) photodetector (PD) application. In addition, a few examples of lanthanide-doped nanostructures with improved performance were discussed, with particular emphasis on upconversion emission enhancement using coupling plasmon. The use of UC materials has been shown to significantly improve the NIR light-harvesting properties of photovoltaic devices and photocatalytic materials. However, the inefficiency of UC emission also prompted the need for additional modification of the optical properties of UC material. This improvement entailed the proper selection of the host matrix and optimization of the sensitizer and activator concentrations, followed by subjecting the UC material to surface-passivation, plasmonic enhancement, or doping. As expected, improving the optical properties of UC materials can lead to enhanced efficiency of PDs and photovoltaic devices.
Interleaving composite laminates by nanofibers is a well-known method of increasing interlaminar fracture toughness. Among many possibilities, polycaprolactone (PCL) nanofibers is one of the best choices for toughening composite laminates. The influence of PCL on delamination mode of failure is considered before. However, the effect of PCL on other damage modes, such as fiber breakage and matrix cracking, is yet to be studied. In this study, the acoustic emission (AE) technique is applied to determine the effect of toughening composite laminates by PCL nanofibers on matrix cracking, fiber/matrix debonding, and fiber breakage failure mechanisms. For this purpose, mode I and mode II fracture tests are conducted on modified and non-modified glass/epoxy laminates. Three different methods, i.e., peak frequency, wavelet transform, and sentry function, are utilized for analyzing the recorded AE data from mode I test. The results show that applying PCL nanofibers not only increases the mode I critical strain energy release rate by about 38%, but also decreases different failure mechanisms by between 75 and 94%.
The geometrical features of nanofibers, such as nanomat thickness and the diameter of nanofibers, have a significant influence on the toughening behavior of composite laminates. In this study, carbon/epoxy laminates were interleaved with polysulfone (PSF) nanofibrous mats and the effect of the PSF nanomat thickness on the fracture toughness was considered for the first time. For this goal, the nanofibers were first produced by the electrospinning method. Then, double cantilever beam (DCB) specimens were manufactured, and mode-I fracture tests were conducted. The results showed that enhancing the mat thickness could increase the fracture toughness considerably (to about 87% with the maximum thickness). The toughening mechanism was also considered by presenting a schematic picture. Micrographs were taken using a scanning electron microscope (SEM).
The nonlinear thermal buckling analysis of functionally graded (FG) beam integrated with shape memory alloy (SMA) layer(s), with different lay-up configurations and supported on a nonlinear elastic foundation, has been investigated. The FG layer is graded through the beam thickness direction and thermomechanical properties are assumed to be temperature dependent. The Brinson one-dimensional constitutive law are used to model the characteristics of SMA. The von Kármán strain–displacement fields with the Timoshenko beam theory are applied to the Hamilton’s principle to derive the set of nonlinear equilibrium equations. Generalized differential quadrature method along with direct iterative scheme is utilized to discretize and solve the nonlinear equilibrium equations. The accuracy of proposed model is compared and validated with previous research in literature. The detailed parametric study has been performed to investigate the influence of geometrical, material, and some other key parameters on the nonlinear thermal buckling solutions. The results show that selecting the proper lay-up is of great importance because the type of SMA/FG lay-up can considerably affect the nonlinear buckling solutions. Moreover, adequate application of SMA layers in a proper lay-up configuration significantly postpones the thermal buckling temperature of the beam.