The consumption of hydrogen could increase by sixfold in 2050 compared to 2020 levels, reaching about 530 Mt. Against this backdrop, the proton exchange membrane fuel cell (PEMFC) has been a major research area in the field of energy engineering. Several reviews have been provided in the existing corpus of literature on PEMFC, but questions related to their evolutionary nuances and research hotspots remain largely unanswered. To fill this gap, the current review uses bibliometric analysis to analyze PEMFC articles indexed in the Scopus database that were published between 2000–2021. It has been revealed that the research field is growing at an annual average growth rate of 19.35%, with publications from 2016 to 2012 alone making up 46% of the total articles available since 2000. As the two most energy-consuming economies in the world, the contributions made towards the progress of PEMFC research have largely been from China and the US. From the research trend found in this investigation, it is clear that the focus of the researchers in the field has largely been to improve the performance and efficiency of PEMFC and its components, which is evident from dominating keywords or phrases such as ‘oxygen reduction reaction’, ‘electrocatalysis’, ‘proton exchange membrane’, ‘gas diffusion layer’, ‘water management’, ‘polybenzimidazole’, ‘durability’, and ‘bipolar plate’. We anticipate that the provision of the research themes that have emerged in the PEMFC field in the last two decades from the scientific mapping technique will guide existing and prospective researchers in the field going forward.

Arguably, one of the most important issues the world is facing currently is climate change. At the current rate of fossil fuel consumption, the world is heading towards extreme levels of global temperature rise if immediate actions are not taken. Transforming the current energy system from one largely based on fossil fuels to a carbon-neutral one requires unprecedented speed. Based on the current state of development, direct electrification of the future energy system alone is technically challenging and not enough, especially in hard-to-abate sectors like heavy industry, road trucking, international shipping, and aviation. This leaves a considerable demand for alternative carbon-neutral fuels such as green ammonia and hydrogen and renewable methanol. From this perspective, we discuss the overarching roles of each fuel in reaching net zero emission within the next three decades. The challenges and future directions associated with the fuels conclude the current perspective paper.