In this study, we found that well-developed α₂′ martensite was formed in a Ti-40Al-10V (atomic percent or at.%) alloy after air-cooling from a β phase field, rather than the traditional α₂/γ lamellar colonies. The martensitic laths were produced according to the Burgers orientation relationship (OR), the same as those during quenching. Local variant selection detected that three (or six) α₂′ variants sharing one (or two) common [11.0]_α2′ axes were predominant, while no global variant selection was observed. Subsequent to the martensitic transformation, the retained β phase was decomposed mainly via a β→γ transformation. The γ laths always nucleated at the α₂′/β interface according to a Blackburn orientation relationship. In order to stabilize the microstructure, the air-cooled samples were tempered at 800–1000 °C. During tempering, the microstructure decomposed mainly via an α₂′→γ transformation. The martensite was almost completely transformed after tempering at 1000 °C for 4 h, and hence a fine β-γ microstructure was obtained. Such a treatment resembling the quenching–tempering in steels may be a new strategy for the microstructural design of TiAl alloys, while an unexpected quenching process can be avoided.

In this study, the deformation behavior of a Ti-40Al-10V (at.%) alloy within β single phase field was examined by means of isothermal compression at 1300 °C under strain rates of 2 s⁻¹, 0.2 s⁻¹, and 0.02 s⁻¹, as well as its effect on the subsequent β→α transformation. The results showed that the alloy behaved steady-state flow with dislocation creep as the predominant rate-controlling process. Dynamic recrystallization (DRX) evidently occurred during deformation, and its volume fraction was dramatically increased so that at the lowest strain rate (0.02 s⁻¹), a full-DRX β structure was obtained. The preferentially dynamic migration of grain boundaries with orientation was demonstrated to be the major DRX mechanism. The texture was characterized by a + double-fiber at 2 s⁻¹, but gradually transformed into a simple rotated cube orientationunder 0.02 s⁻¹, accompanied by a decreasing texture intensity. During the subsequent β→α transformation, two types of α morphology wereproduced with evident variant selection, namely, the Widmannstatten colony and martensitic laths. Texture simulation revealed that the α texture was solely determined by parent β texture, despite of the variant selections.

In this study, a Ti-40Al-10V alloy with quenching-tempering microstructure was prepared and was characterized by ultra-large β/B2 grains and submicrocrystalline γ laths within it. A definite Kurdjumov-Sachs orientation was identified between the β/B2 and γ phase. Isothermal compression tests were performed to examine the hot deformation behavior at various temperatures and strain rates. Based on the hyperbolic-sine equation, the deformation kinetics of the alloy were characterized by unexpectedly high activation energy (384 kJ/mol) and low stress exponent (2.25). For all the deformed samples, continuous dynamic recrystallization intensively occurred in the β matrix, accompanied by the simultaneous rotation of the γ laths. Moreover, a preferential orientation of _β and _γ parallel to the compression axis was observed for β and γ phase, respectively. With the decreasing strain rates, the grain boundary/interface sliding gradually became prominent, which resulted in some superplastic deformation features, e.g., intensive strain-induced grain growth and interface migration, enhancing “wetting” of the γ grain boundaries, continuous weakening/vanishing of the local texture, etc. Meanwhile, the temperature played an insignificant role in the hot deformation behavior. The deformation mechanism was discussed in detail based on the microstructural observations and deformation kinetics.