The utilization of greens resources is a grand challenge for this century. A lot of efforts are paid to substitute toxic ingredients of the conventional drilling mud system with nontoxic natural materials. In this paper, the effect of the natural polymer chitosan on the rheology and stability of sodium-bentonite drilling mud was investigated in the polymer concentration range of 0.1–3.0 wt.%. Both the shear and time dependent rheological properties of pure chitosan, pure bentonite and bentonite–chitosan dispersions were studied. Moreover, zeta potential measurements were used to evaluate the stability of bentonite-chitosan suspension. Adding chitosan improved the natural properties of drilling mud, namely: yield stress, shear thinning, and thixotropy. The viscosity of bentonite suspension increased significantly upon the addition of chitosan in the concentration range of 0.5 to 3.0 wt.% forming network structure, which can be attributed to the interactions of hydrogen bonding between -OH clusters on the bentonite surface with the NH group in the chitosan structure. On the other hand, dispersed chitosan–bentonite suspension was observed at low chitosan concentration (less than 0.5 wt.%). Increasing both bentonite and chitosan concentrations led to the flocculation of the bentonite suspension, forming a continuous gel structure that was characterized by noteworthy yield stress. The desired drilling mud rheological behavior can be obtained with less bentonite by adding chitosan polymer and the undesirable effects of high solid clay concentration can be avoided.

This experimental assessment was carried out to study the viscoelastic performance of crude oil-xanthan emulsions employing a RheoStress RS100 rheometer. Crude oil with a concentration range of 0–75% by volume was used to prepare the oil-gum emulsions. Two xanthan gums of Sigma and Kelzan were added in the emulsions with concentration ranges of 0–10⁴ ppm. The linear viscoelastic ranges of all the tested oil-gum emulsions were found in the range of 0.1–10 Pa. Thus, the experimental tests were completed within the linear viscoelastic range of 1 Pa. The complex modulus increased gradually and steadily with frequency and gum concentration for all the examined emulsions. The addition of crude oil into the lighter xanthan concentration of <10³ ppm provided almost the same behavior as the xanthan solution, whereas the presence of crude oil within the higher xanthan concentrations significantly stimulated the measured values of the complex modulus. For lower gum concentrations of up to 1000 ppm, oil concentration displayed no effect on both the storage and loss moduli, whereas for gum concentrations higher than 1000 ppm, both moduli increased gradually with crude oil concentration.

The experimental study of the Creep-recovery examination is necessary to understand the viscoelastic behavior of crude oil-Xanthan gum emulsions. The experimental measurements and analysis of these tests were completed using RheoStress RS100 under controlled stress CS-mode. Rheometers with CS-mode allow for a useful and direct technique for the experimental measurements of creep and recovery stages. This investigation covers a wide range of crude oil concentration of 0–75% by volume, Xanthan concentration range of 0–10⁴ ppm, and two types of Xanthan gums are used and investigated. The creep-recovery measurements of crude oil-Xanthan gums emulsions were extensively investigated. It was important to find the linear viscoelastic range for the examined crude oil-Xanthan gum emulsions. The experimental measurements and analysis of the creep-recovery examinations showed that the linear viscoelastic range was up to 1 Pa. The experimental investigation showed that the higher the concentration of the used gum and crude oil, the lower the compliance of the emulsions. For the Xanthan concentrations of less than 10³ ppm, the crude oil-gum emulsion exhibited viscous behavior. However, for the Xanthan concentration of higher than 10³, the examined emulsions displayed viscoelastic behavior.