The rapid relaxation of above-bandgap “hot” carriers (HCs) imposes the key efficiency limit in lead-halide perovskite (LHP) solar cells. Recent studies have indicated that HC cooling in these systems may be sensitive to materials composition, as well as the energy and density of excited states. However, the key parameters underpinning the cooling mechanism are currently under debate. Here we use a sequence of ultrafast optical pulses (visible pump-infrared push-infrared probe) to directly compare the intraband cooling dynamics in five common LHPs: FAPbI₃, FAPbBr₃, MAPbI₃, MAPbBr₃ and CsPbBr₃. We observe ~100-900 fs cooling times, with slower cooling at higher HC densities. This effect is strongest in the all-inorganic Cs-based system, compared to the hybrid analogues with organic cations. These observations, together with band structure calculations, allow us to quantify the origin of the “hot-phonon bottleneck” in LHPs, and assert the thermodynamic contribution of a symmetry-breaking organic cation towards rapid HC cooling.

Terahertz pulse time-domain holography (THz PTDH) is the powerful technique for high-resolution amplitude and phase THz imaging that allows mapping spectroscopic information across the imaged object. In this paper, we consider most sought after applications of phase imaging provided by this technique and experimentally demonstrate the ability of the method to reconstruct smooth and stepped relief features of an object that is transparent in THz region. Unlike the amplitude distribution, which does not contain any significant information in this case, phase distribution not only reveals the object qualitatively, but also allows the reconstruction of the object thicknesses pattern, even in low signal-to-noise registration conditions. Main limitations of the proposed method, such as transverse resolution and low signal-to-noise environment are carefully studied and mitigated.

Advanced nanophotonics penetrates into other areas of science and technology, ranging from applied physics to biology, which results in many fascinating cross-disciplinary applications. It has been recently demonstrated that suitably engineered light-matter interactions at the nanoscale can overcome the limitations of today’s terahertz (THz) photoconductive antennas, making them one step closer to many practical implications. Here, we push forward this concept by comprehensive numerical optimization and experimental investigation of a log-periodic THz photoconductive antenna coupled to a silver nanoantenna array. We shed light on the operation principles of the resulting hybrid THz antenna, providing an approach to boost its performance. By tailoring the size of silver nanoantennas and their arrangement, we obtain an enhancement of optical-to-THz conversion efficiency 2-fold larger compared with previously reported results for similar structures, and the strongest enhancement is around 1 THz, a frequency range barely achievable by other compact THz sources. We also propose a cost-effective fabrication procedure to realize such hybrid THz antennas with optimized plasmonic nanostructures via thermal dewetting process, which does not require any post processing and makes the proposed solution very attractive for applications.

We propose a comprehensive physical model explaining the conical character of broadband terahertz generation from femtosecond two-color laser-induced air plasma filaments. We show, that, in contrast to other models, emission is always conical, resulting from phase matching of the radiation produced inside the filament combined with a partial back reflection of the generated terahertz field from the filament itself due to the frequency-dependent critical plasma density. The obtained conical angle varies from 2${}^{$\circ${}}$ to 10${}^{$\circ${}}$, depending on the plasma density distribution and filament length. Unlike previously proposed models, our model shows good agreement with our experiments as well as a wide range of experimental findings from the literature.

Terahertz time-domain spectroscopy (THz–TDS) has been applied for the detection and discrimination of harmful chemical residues in honey. Three antibiotics (sulfapyridine, sulfathiazole, and tetracycline) and two acaricides (coumaphos and amitraz) were characterized in the THz frequency regime between 0.5 THz and 6.0 THz. All chemical substances present distinct absorption peaks. THz transmission measurements of honey mixtures with antibiotics have been performed, revealing that antibiotic residues are traceable in highly absorptive food products, such as honey, at concentrations down to 1% weight percentage, thanks to their THz fingerprints. Moreover, multiple antibiotics were identified in their mixture with honey, pointing out the potential of the technique to be used in the near future as a fast, real-time technique for detecting and discriminating multi-residues strictly related to food safety issues.