The unknown temperature of a sample can be estimated with minimal disturbance by putting it in thermal contact with an individual quantum probe. If the interaction time is sufficiently long so that the probe thermalizes, the temperature can be read-out directly from its steady state. Here we prove that the optimal quantum probe, acting as a thermometer with maximal thermal sensitivity, is an effective two-level atom with a maximally degenerate excited state. When the total interaction time is insufficient to produce full thermalization, we optimize the estimation protocol by breaking it down into sequential stages of probe preparation, thermal contact, and measurement. We observe that frequently interrogated probes initialized in the ground state achieve the best performance. For both fully and partly thermalized thermometers, the sensitivity grows significantly with the number of levels, though optimization over their energy spectrum remains always crucial.

Controlling and measuring the temperature in different devices and platforms that operate in the quantum regime is, without any doubt, essential for any potential application. In this review, we report the most recent theoretical developments dealing with accurate estimation of very low temperatures in quantum systems. Together with the emerging experimental techniques and developments of measurement protocols, the theory of quantum thermometry will decisively impinge and shape the forthcoming quantum technologies. While current quantum thermometric methods differ greatly depending on the experimental platform, the achievable precision, and the temperature range of interest, the theory of quantum thermometry is built under a unifying framework at the crossroads of quantum metrology, open quantum systems, and quantum many-body physics. At a fundamental level, theoretical quantum thermometry is concerned with finding the ultimate bounds and scaling laws that limit the precision of temperature estimation for systems in and out of thermal equilibrium. At a more practical level, it provides tools to formulate precise, yet feasible, thermometric protocols for relevant experimental architectures. Last but not least, the theory of quantum thermometry examines genuine quantum features, like entanglement and coherence, for their exploitation in enhanced-resolution thermometry.

Estimation of parameters is a pivotal task throughout science and technology. The quantum Cram\'er-Rao bound provides a fundamental limit of precision allowed to be achieved under quantum theory. For closed quantum systems, it has been shown how the estimation precision depends on the underlying dynamics. Here, we propose a general formulation for metrology scenarios in open quantum systems, aiming to relate the precision more directly to properties of the underlying dynamics. This feature may be employed to enhance an estimation precision, e.g., by quantum control techniques. Specifically, we derive a Cram\'er-Rao bound for a fairly large class of open system dynamics, which is governed by a (time-dependent) dynamical semigroup map. We illustrate the utility of this scenario through three examples.

We consider the problem of estimating the temperature $T$ of a very cold equilibrium sample. The temperature estimates are drawn from measurements performed on a quantum Brownian probe strongly coupled to it. We model this scenario by resorting to the canonical Caldeira-Leggett Hamiltonian and find analytically the exact stationary state of the probe for arbitrary coupling strength. In general, the probe does not reach thermal equilibrium with the sample, due to their nonperturbative interaction. We argue that this is advantageous for low-temperature thermometry, as we show in our model that (i) the thermometric precision at low $T$ can be significantly enhanced by strengthening the probe-sampling coupling, (ii) the variance of a suitable quadrature of our Brownian thermometer can yield temperature estimates with nearly minimal statistical uncertainty, and (iii) the spectral density of the probe-sample coupling may be engineered to further improve thermometric performance. These observations may find applications in practical nanoscale thermometry at low temperatures—a regime which is particularly relevant to quantum technologies.

We introduce a novel minimally disturbing method for sub-nK thermometry in a Bose-Einstein condensate (BEC). Our technique is based on the Bose polaron model; namely, an impurity embedded in the BEC acts as the thermometer. We propose to detect temperature fluctuations from measurements of the position and momentum of the impurity. Crucially, these cause minimal backaction on the BEC and hence, realize a nondemolition temperature measurement. Following the paradigm of the emerging field of quantum thermometry, we combine tools from quantum parameter estimation and the theory of open quantum systems to solve the problem in full generality. We thus avoid any simplification, such as demanding thermalization of the impurity atoms, or imposing weak dissipative interactions with the BEC. Our method is illustrated with realistic experimental parameters common in many labs, thus showing that it can compete with state-of-the-art destructive techniques, even when the estimates are built from the outcomes of accessible (suboptimal) quadrature measurements.