Lotus flowers, rose petals, some plant leaves and insects have a naturally super-hydrophobic surface. In fact, the surface of a Lotus leaf is covered by micro and nano structures mixed with wax, which makes its surface superhydrophobic. In microfluidics, superhydrophobicity is an important factor in the rheometers on a chip. It is also sought in other complex fluids applications like the self-cleaning and the antibacterial materials. The wettability of the surface of solid support can be modified by altering its chemical composition. This means functionalizing the interface molecules to different chemical properties, and/or forming a thin film on the surface. We can also influence its texturing by changing its roughness. Despite considerable efforts during the last decade, superhydrophobic surfaces usually involve, among others, microfabrication processes, such as photolithography technique. In this study, we propose an original and simple method to create superhydrophobic surfaces by controlling elastic instability of poly-dimethylsiloxane (PDMS) films. Indeed, we demonstrate that the self-organization of wrinkles on top of non-wettable polymer surfaces leads to surperhydrophobic surfaces with contact angles exceeding 150°. We studied the transition Wenzel-Cassie, which indicated that the passage of morphology drops “impaled” to a type of morphology “fakir” were the strongest topographies.
Certain plants like Rosemarinus officinalis, Lavandula angustifolia and Origanum vulgare have been used in the food industry for centuries. Cymbopogon winterianus (Java Citronella plant) is one of the most significant plants. The objective of this study is to screen for secondary metabolites by phytochemical screening, evaluate the antioxidant contents of extracts and investigate the use of the Java Citronella plant in food preservation and as an insecticide. Java Citronella powder was added to bread and evaluated for its moisture content, and a visual and sensory analysis was performed. Sitophilus granarius (L.) weevils were exposed to Java Citronella essential oil (JCEO). The phytochemical screening revealed that the extracts were abundant in secondary metabolites. The JCEO had a yield of 0.75%. The aqueous extract had a higher total phenolic content of 49.043 ± 0.217 mg GAE/g than the ethanolic extract, which was 24.478 ± 1.956 mg GAE/g. The aqueous extract had a total flavonoids content 27,725.25 ± 54.96 µg RE/g higher than the ethanolic extract, with 24,263 ± 74 µg RE/g. The ethanolic extract had stronger antioxidant activity, with anIC50 = 196.116 μg/mL higher than the aqueous extract at 420 μg/mL. The 2% Java Citronella powder in the bread was preferred by consumers, and had a shelf life of 6 days. JCEO killed all the weevils with a high dose of 10% after 48 h. The Java Citronella showed insecticidal and food preservative activity. The results should help in future research to enhance the applications of Java Citronella in various domains, from food technology to insecticides.
The wettability of materials is a very important aspect of surface science governed by the chemical composition of the surface and its morphology. In this context, materials replicating nature's superhydrophobic surfaces, such as lotus leafs, rose petals and butterfly wings, have widely attracted attention of physicists and material engineers [1–3]. Despite of considerable efforts during the last decade, superhydrophobic surfaces are still expensive and usually involved microfabrication processes, such as photolithography technique. In this study, we propose an original and simple method to create superhydrophobic surfaces by controling elastic instabilities [4–8]. Indeed, we demonstrate that the self-organization of wrinkles on top of non-wettable polymer surfaces leads to surperhydrophobic surfaces
1 January 2016 in International Journal of Sciences
Plant leaves, insect wings, and other natural surfaces show interesting cases of out-of-plan deformations, which can be attributed to mechanical buckling. This paper deals with a specific type of elastic instabilities, where both microscopic (wrinkles) and macroscopic (global curvature) deformations occur simultaneously. To this end, PDMS narrow sheet was stretched, its surface oxidized, then released. Its deformation was measured and analyzed. A mechanical model considering the effect of wrinkle on elasticity was elaborated; the concept equivalent stiffness was introduced in order to represent this effect. The model was matched with testing results successfully. This model is an interesting tool to explain potentially number of elastic instability phenomena.