The Phanerozoic tectonothermal evolution of the SW slope of the East European Platform (EEP) in Poland is reconstructed by means of thermal maturity, low-temperature thermochronometry, and thermal modelling. We provide a set of new thermochronometric data and integrate stratigraphic and thermal maturity information to constrain the burial and thermal history of sediments. Apatite fission track (AFT) analysis and zircon $(\mathrm{U}-\mathrm{Th})/\mathrm{He}$ (ZHe) thermochronology have been carried out on samples of sandstones, bentonites, diabase, and crystalline basement rocks collected from 17 boreholes located in central and NE Poland. They penetrated sedimentary cover of the EEP subdivided from the north to south into the Baltic, Podlasie, and Lublin basins. The average ZHe ages from Proterozoic basement rocks as well as Ordovician to Silurian bentonites and Cambrian to lower Carboniferous sandstones range from 848 ± 81 to 255 ± 22 Ma with a single early Permian age of 288 Ma, corresponding to cooling after a thermal event. The remaining ZHe ages represent partial reset or source ages. The AFT ages of samples are dispersed in the range of 235.8 ± 17.3 Ma (Middle Triassic) to 42.1 ± 11.1 Ma (Paleogene) providing a record of Mesozoic and Cenozoic cooling. The highest frequency of the AFT ages is in the Jurassic and Early Cretaceous prior to Alpine basin inversion. Thermal maturity results are consistent with the SW-ward increase of the Paleozoic and Mesozoic sediments thickness. An important break in a thermal maturity profile exists across the base Permian–Mesozoic unconformity. Thermal modelling showed that significant heating of Ediacaran to Carboniferous sedimentary successions occurred before the Permian with maximum paleotemperatures in the earliest and latest Carboniferous for Baltic–Podlasie and Lublin basins, respectively. The results obtained suggest an important role of early Carboniferous uplift and exhumation at the SW margin of the EEP. The SW slope of the latter was afterward overridden in the Lublin Basin by the Variscan orogenic wedge. Its tectonic loading interrupted Carboniferous uplift and caused resumption of sedimentation in the late Viséan. Consequently, a thermal history of the Lublin Basin is different from that in the Podlasie and Baltic basins but similar to other sections of the Variscan foreland, characterized by maximum burial at the end of Carboniferous. The Mesozoic thermal history was characterized by gradual cooling from peak temperatures at the transition from Triassic to Jurassic due to decreasing heat flow. Burial caused maximum paleotemperatures in the SW part of the study area, where the EEP was covered by an extensive sedimentary pile. However, further NE, due to low temperatures caused by shallow burial, the impact of fluids can be detected by vitrinite reflectance, illite/smectite, and thermochronological data. Our new results emphasize the importance of using multiple low-temperature thermochronometers and thermal modelling in connection with thermal maturity analysis to elucidate the near-surface evolution of platform margins.

The Intra-Sudetic Basin, a ~ 12 km deep Variscan intramontane basin, has the best preserved post-orogenic sedimentary record available at the NE margin of the Bohemian Massif. Apatite fission track (AFT) analyses have been performed on 16 sedimentary and volcanic samples of Carboniferous to Cretaceous age from the Intra-Sudetic Basin to improve understanding of the post-Variscan thermal evolution. AFT central ages range from 50.1 ± 8.8 to 89.1 ± 7.1 Ma (Early Eocene to Coniacian), with 13 of them being Late Cretaceous. The mean track length values range from 12.5 ± 0.4 to 13.8 ± 0.5 (except for one sample 14.4 ± 0.2) µm. This relatively short mean track length together with the unimodal track length distributions and rather low standard deviation (0.8 to 1.7 µm) in most samples indicate a long stay in the partial annealing zone during slow cooling. However, in the northern part of the Intra-Sudetic Basin, samples show a wider track length distribution (standard deviation of 1.8 to 2.1 µm) that could indicate a more complex thermal evolution possibly related to Mesozoic reheating. Vitrinite reflectance data combined with thermal models based on the AFT results indicate that the Carboniferous strata reached maximum palaeotemperatures in the latest Carboniferous to Early Permian time, corresponding to a major coalification event. The second phase of temperature rise occurred due to Late Mesozoic sedimentary burial, but it had no influence on maturation of the Carboniferous organic matter. Final cooling phase in the Late Cretaceous–Paleogene was related to tectonic inversion of the Intra-Sudetic Basin, which occurred after deposition of a significant thickness of Cenomanian–Turonian sediments. Thermal modelling demonstrates that ~ 4 km thick cover of Upper Cretaceous sediments is required to obtain a good match between our AFT data and modelled time–temperature paths. This outcome supports a significant amount of Late Cretaceous–Paleogene inversion within the Variscan belt of Central Europe.

The concentration of critical elements, including such REE as Fe, Co, W, Zn, Cr, Ni, V, Mn, Ti, Ag, Ga, Ta, Sr, Li, and Cu, in the so-called fly ash obtained from the 9 Polish power plants and 1 thermal power station has been determined. The obtained values, compared with the global average concentration in bituminous coal ash and sedimentary rocks (Clarke values), have shown that the enrichment of fly ash in the specified elements takes place in only a few bituminous coal processing sites in Poland. The enrichment factor (EF) is only slightly higher (the same order of magnitude) than the Clarke values. The enrichment factor in relation to the Clarke value in the Earth’s crust reached values above 10 in all of the examined ashes for the following elements: Cr, Ni, V, W, and, in some ash samples, also Cu and Zn. The obtained values are low, only slightly higher than the global average concentrations in sedimentary rocks and bituminous coal ashes. The ferromagnetic grains (microspheres) found in bituminous coal fly ashes seem to be the most economically prospective in recovery of selected critical elements. The microanalysis has shown that iron cenospheres and plerospheres in fly ash contain, in addition to enamel and iron oxides (magnetite and hematite), iron spinels enriched in Co, Cr, Cu, Mn, Ni, W, and Zn.