Guang-Han Cao

Prof. Dr. Guang-Han Cao

Department of Physics, Zhejiang University, Hangzhou 310027, China
orcid

Research Focus & Metrics

Academic Career Length

30Years (1997-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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1 April 2009 in Physical Review Letters
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Journal Article
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ZRZhi Ren
Zhi Ren
QTQian Tao
Qian Tao
SJShuai Jiang
Shuai Jiang
CFChunmu Feng
Chunmu Feng
CWCao Wang
Cao Wang
ZXZhu’aN Xu
Zhu’aN Xu
We have studied EuFe2(As0.7P0.3)2 by the measurements of x-ray diffraction, electrical resistivity, thermopower, magnetic susceptibility, magnetoresistance, and specific heat. Partial substitution of As with P results in the shrinkage of lattice, which generates chemical pressure to the system. It is found that EuFe2(As0.7P0.3)2 undergoes a superconducting transition at 26 K, followed by ferromagnetic ordering of Eu2+ moments at 20 K. This finding is the first observation of superconductivity stabilized by internal chemical pressure, and supplies a rare example showing the coexistence of superconductivity and ferromagnetism in the ferroarsenide family.

9 February 2015 in Physical Review X
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JBJin-Ke Bao
Jin-Ke Bao
JLJi-Yong Liu
Ji-Yong Liu
CMCong-Wei Ma
Cong-Wei Ma
ZMZhi-Hao Meng
Zhi-Hao Meng
ZTZhang-Tu Tang
Zhang-Tu Tang
Guang-Han CaoGuang-Han Cao
Guang-Han Cao
We report the discovery of bulk superconductivity (SC) at 6.1 K in a quasi-one-dimensional chromium pnictide K2Cr3As3 that contains [(Cr3As3)2−]∞ double-walled subnanotubes with face-sharing Cr6/2 (As6/2) octahedron linear chains in the inner (outer) wall. The material has a large electronic specific-heat coefficient of 70–75  mJ K−2 mol−1, indicating significantly strong electron correlations. A linear temperature dependence of resistivity in a broad temperature range from 7 to 300 K is observed, which suggests non-Fermi liquid behavior of the material. Unconventional SC is preliminarily manifested by the estimated upper critical field exceeding the Pauli limit by a factor of 3–4. The title compound represents a rare example that possibly unconventional SC emerges in a quasi-1D system with strong electron correlations.

1 February 2009 in New Journal of Physics
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LLL J Li
L J Li
YLY K Luo
Y K Luo
QWQ B Wang
Q B Wang
HCH Chen
H Chen
ZRZ Ren
Z Ren
ZXZ A Xu
Z A Xu
A series of 122 phase BaFe$_{2-x}$Ni$_x$As$_2$ ($x$ = 0, 0.055, 0.096, 0.18, 0.23) single crystals were grown by self flux method and a dome-like Ni doping dependence of superconducting transition temperature is discovered. The transition temperature $T_c^{on}$ reaches a maximum of 20.5 K at $x$ = 0.096, and it drops to below 4 K as $x$ $\geq$ 0.23. The negative thermopower in the normal state indicates that electron-like charge carrier indeed dominates in this system. This Ni-doped system provides another example of superconductivity induced by electron doping in the 122 phase.

31 March 2025 in Nature Physics
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FZFayuan Zhang
Fayuan Zhang
XCXingkai Cheng
Xingkai Cheng
ZYZhouyi Yin
Zhouyi Yin
CLChangchao Liu
Changchao Liu
LDLiwei Deng
Liwei Deng
CCChaoyu Chen
Chaoyu Chen

30 January 2015 in Physical Review B
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ZTZhang-Tu Tang
Zhang-Tu Tang
JBJin-Ke Bao
Jin-Ke Bao
YLYi Liu
Yi Liu
YSYun-Lei Sun
Yun-Lei Sun
AAAbduweli Ablimit
Abduweli Ablimit
Guang-Han CaoGuang-Han Cao
Guang-Han Cao
Following the discovery of superconductivity in quasi-one-dimensional K2Cr3As3 containing [(Cr3As3)2−]∞ chains (J. K. Bao et al., arXiv:1412.0067), we succeeded in synthesizing an analogous compound, Rb2Cr3As3, which also crystallizes in a hexagonal lattice. The replacement of K by Rb results in an expansion of the a axis by 3%, indicating a weaker interchain coupling in Rb2Cr3As3. Bulk superconductivity emerges at 4.8 K, above which the normal-state resistivity shows a linear temperature dependence up to 35 K. The estimated upper critical field at zero temperature exceeds the Pauli paramagnetic limit by a factor of 2. Furthermore, the electronic specific-heat coefficient extrapolated to zero temperature in the mixed state increases with H, suggesting the existence of nodes in the superconducting energy gap. Hence Rb2Cr3As3 manifests itself as another example of an unconventional superconductor in the Cr3As3-chain based system.

5 August 2008 in Physical Review B
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Journal Article
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ZRZhi Ren
Zhi Ren
ZZZengwei Zhu
Zengwei Zhu
SJShuai Jiang
Shuai Jiang
XXXiangfan Xu
Xiangfan Xu
QTQian Tao
Qian Tao
ZXZhu’aN Xu
Zhu’aN Xu
Ternary iron arsenide EuFe2As2 with ThCr2Si2-type structure has been studied by magnetic susceptibility, resistivity, thermopower, Hall, and specific-heat measurements. The compound undergoes two magnetic phase transitions at about 200 and 20 K, respectively. The former was found to be accompanied with a slight drop in magnetic susceptibility (after subtracting the Curie-Weiss paramagnetic contribution), a rapid decrease in resistivity, a large jump in thermopower, and a sharp peak in specific heat with decreasing temperature, all of which point to a spin-density-wave-like antiferromagnetic transition. The latter was proposed to be associated with an A-type antiferromagnetic ordering of Eu2+ moments. Comparing with the physical properties of the isostructural compounds BaFe2As2 and SrFe2As2, we expect that superconductivity could be induced in EuFe2As2 through appropriate doping.