We have measured the electron drift velocity, longitudinal diffusion, and the effective ionization coefficients in the gaseous mixture of CF3I–SF6 over the density-normalized electric field intensity E/N, from 375 to 500 Td (1 Td = 10−17 V cm2). A pulsed Townsend technique was used. Overall, the gas mixture compositions were varied from 50 to 90% CF3I. We have found that the limiting field strength E/Nlim of the CF3I–SF6 mixture is superior to that of CF3I–N2, and always higher than that of SF6. Moreover, over the whole mixture range, the range of the limiting field strength for the CF3I–SF6 mixture is 360–437 Td, these limits corresponding for pure SF6 and CF3I, respectively.
1 June 2019 in Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
Adobe masonry is one of the oldest construction systems still in use today, Mexico has an enormous cultural heritage with traditional adobe houses being very representative of the rural communities and their culture. The 2017 Puebla Earthquake on September 19th struck the country causing the loss, destruction, and damage of historic buildings in several Mexican states, with the traditional earthen dwellings being the most vulnerable structures to these events. The fast abandonment of the local materials and techniques entails further research regarding the characterization of these construction systems, therefore, reconstruction efforts first require the recovery of the construction technique. After the seismic events, adobe samples of the remaining adobe structures of Jojutla de Juarez were collected. This population was one of the most affected in all the country, and, because of the major losses suffered, the study was conducted to determine the material properties of the dwellings’ adobe shards and natural quarry clays of the region. The characterization included destructive and non-destructive tests, mineralogical and granulometry analyses, and composition of the adobe samples of the buildings, as well as the aggregates. As a novelty, the compressive strength of the pieces was tested by two methods: the traditional compression strength test and the point-load test, in order to obtain the indicative values and the correlation equations between both tests. From the formal analysis and the laboratory, it was observed that the adobes from Jojutla presented different compositions which combined with the building malpractices and alterations to the traditional systems caused unpredictable behavior during the earthquake. The conduction of point-load tests in situ, as a part of a complete characterization methodology, could be an alternative to study the mechanical properties of patrimonial or damaged building samples before its disappearance.
13 December 2016 in Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences
Colonial panel paintings constitute an essential part of Latin-American cultural heritage. Their study is vital for understanding the manufacturing process, including its evolution in history, as well as its authorship, dating and other information significant to art history and conservation purposes. Raman spectroscopy supplies a non-destructive characterization tool, which can be implemented for in situ analysis, via portable equipment. Specific methodologies must be developed, comprising the elaboration of reference panel paintings using techniques and materials similar to those of the analysed period, as well as the determination of the best analysis conditions for different pigments and ground preparations. In order to do so, Raman spectroscopy at 532, 785 and 1064 nm, surface-enhanced Raman spectroscopy (SERS) and a helium-Raman system were applied to a panel painting reference, in combination with X-ray fluorescence analysis. We were able to establish the analysis conditions for a number of sixteenth century pigments and dyes, and other relevant components of panel paintings from this period, 1064 nm Raman and SERS being the most successful. The acquired spectra contain valuable specific information for their identification and they conform a very useful database that can be applied to the analysis of Ibero-American Colonial paintings. This article is part of the themed issue ‘Raman spectroscopy in art and archaeology’.
Jadeite was greatly appreciated by pre-Hispanic cultures in Mesoamerica. Despite its importance, knowledge of its mining sources was lost after the Spanish conquest. In the 1950s the only confirmed jadeite deposits in Mesoamerica were found in the Motagua River Fault (MRF), Guatemala. The aim of this study is to present a methodology that is appropriate for the study of archeological jadeite objects using non-destructive spectroscopic and micro-ion beam analysis techniques. This methodology has been applied to perform mineral, elemental, and luminescence characterization of five jadeite samples from the MRF, with white, lilac, and green colors. Fourier-transformed infrared spectroscopy and X-ray diffraction analysis confirmed the presence of jadeite, albite, and omphacite as the main mineral phases in the samples. Elemental maps using particle-induced X-ray emission (PIXE) with a nuclear microprobe and elemental concentration analysis from individual mineral grains using micro-PIXE coupled with micro-ionoluminescence (IL) allowed the detection of minor feldspar, titanite, and grossular mineral contents. Distinctive features from the mineral, elemental, and luminescence characterization have been found that allow the identification of these five jadeite samples.