The assessment of soil elemental concentrations nowadays mainly occurs through conventional laboratory analyses. However, proximal soil sensing (PSS) techniques such as X-ray fluorescence (XRF) spectrometry are proving to reduce analysis time and costs, and thus offer a worthy alternative to laboratory analyses. Moreover, XRF scanners are non-destructive and can be directly employed in the field. Although the use of XRF for soil elemental analysis is becoming widely accepted, most previous studies were limited to one scanner, a few samples, a few elements, or a non-diverse sample database. Here, an extensive and diverse soil database was used to compare the performance of three different XRF scanners with results obtained through conventional laboratory analyses. Scanners were used in benchtop mode with built-in soil calibrations to measure the concentrations of 15 elements. Although in many samples Cu, S, P, and Mg concentrations were up to 6, 12, 13, and 5 times overestimated by XRF, and empirical recalibration is recommended, all scanners produced acceptable results, even for lighter elements. Unexpectedly, XRF performance did not seem to depend on soil characteristics such as CaCO3 content. While performances will be worse when expanding to the field, our results show that XRF can easily be applied by non-experts to measure soil elemental concentrations reliably in widely different environments.
In this study, we present zircon U/Pb, plagioclase and K-feldspar 40Ar/39Ar and apatite fission track (AFT) data along the South Tannuol Fault Zone (STFZ). Integrating geochronology and multi-method thermochronology places constraints on the formation and subsequent reactivation of the STFZ. Cambrian (~510 Ma) zircon U/Pb ages obtained for felsic volcanic rocks date the final stage of STFZ basement formation. Ordovician (~460–450 Ma) zircon U/Pb ages were obtained for felsic rocks along the structure, dating their emplacement and marking post-formational local magmatic activity along the STFZ. 40Ar/39Ar stepwise heating plateau-ages (~410–400 Ma, ~365 and ~340 Ma) reveal Early Devonian and Late Devonian–Mississippian intrusion and/or post-magmatic cooling episodes of mafic rocks in the basement. Permian (~290 Ma) zircon U/Pb age of mafic rocks documents for the first time Permian magmatism in the study area creating prerequisites for revising the spread of Permian large igneous provinces of Central Asia. The AFT dating and Thermal history modeling based on the AFT data reveals two intracontinental tectonic reactivation episodes of the STFZ: (1) a period of Cretaceous–Eocene (~100–40 Ma) reactivation and (2) the late Neogene (from ~10 Ma onwards) impulse after a period of tectonic stability during the Eocene–Miocene (~40–10 Ma).
The West Siberian Basin (WSB) is one of the largest intracratonic Meso-Cenozoic basins in the world. Its evolution has been studied over the recent decades; however, some fundamental questions regarding the tectonic evolution of the WSB remain unresolved or unconfirmed by analytical data. A complete understanding of the evolution of the WSB during the Mesozoic and Cenozoic eras requires insights into the cooling history of the basement rocks as determined by low-temperature thermochronometry. We presented an apatite fission track (AFT) thermochronology study on the exposed parts of the WSB basement in order to distinguish tectonic activation episodes in an absolute timeframe. AFT dating of thirteen basement samples mainly yielded Cretaceous cooling ages and mean track lengths varied between 12.8 and 14.5 μm. Thermal history modeling based on the AFT data demonstrates several Mesozoic and Cenozoic intracontinental tectonic reactivation episodes affected the WSB basement. We interpreted the episodes of tectonic activity accompanied by the WSB basement exhumation as a far-field effect from tectonic processes acting on the southern and eastern boundaries of Eurasia during the Mesozoic–Cenozoic eras.
Wood and charcoal were key sources of energy during early industrialization in Europe (18th century), preceding the large-scale exploitation of fossil coal. Past timber harvesting implied land transformation and woodland resources management. Therefore, relict charcoal kilns and historical documents of forest management are important sources of information about past woodland composition and structure. However, ancient charcoal kilns are poorly documented in temperate woodlands in the lowlands of western Europe, especially combined with historical written sources. In this study, charcoal production was investigated in an area in NE France, by combining charcoal and historical sources analysis, along with innovative dating methodologies. Thus, by using both radiocarbon and optically-stimulated luminescence dating, we showed that the activity lasted until recent times (19th–early 20th centuries) and Carpinus was the dominant taxon in charcoal assemblage. Moreover, kiln attributes seemed to be independent of topographical variables. Woodlands in this area were subject to a coppice-with-standards management, where small diameter wood was preferred to produce charcoal and large diameter stems, mainly Quercus and Fagus, were traded as timber. The dominance of Carpinus is rather uncommon in charcoal studies but supports the importance of Carpinus as fuelwood since the Middle Ages, as confirmed by many written sources.