Tribology involves the study of friction, wear, lubrication, and adhesion, including biomimetic superhydrophobic and icephobic surfaces. The three aspects of icephobicity are the low ice adhesion, repulsion of incoming water droplets prior to freezing, and delayed frost formation. Although superhydrophobic surfaces are not always icephobic, the theoretical mechanisms behind icephobicity are similar to the entropically driven hydrophobic interactions. The growth of ice crystals in saturated vapor is partially governed by entropically driven diffusion of water molecules to definite locations similarly to hydrophobic interactions. The ice crystal formation can be compared to protein folding controlled by hydrophobic forces. Surface topography and surface energy can affect both the icephobicity and hydrophobicity. By controlling these properties, micro/nanostructured icephobic concrete was developed. The concrete showed ice adhesion strength one order of magnitude lower than regular concrete and could repel incoming water droplets at −5 °C. The icephobic performance of the concrete can be optimized by controlling the sand and polyvinyl alcohol fiber content.
28 August 2015 in Physical Chemistry Chemical Physics
Lotus (Nelumbo nucifera) is known for its two remarkable properties: superhydrophobicity and thermogenesis; however, the relationship between these two properties remains obscure. Most botanists agree that thermogenesis helps to attract pollinators, while non-wetting helps to catch pollinators and prevents contamination. Here we investigate the surface micro- and nanotopography and wetting properties of eastern skunk cabbage (Symplocarpus foetidus), another thermogenic plant, which is known for its ability to melt snow. The skunk cabbage leaves are hydrophobic but not superhydrophobic, and they have high contact angle hysteresis (similar to the rose petal effect). We develop a heat transfer model to relate icephobicity with heat transfer and discuss the biomimetic potential that both thermogenic and superhydrophobic plants may have for icephobicity in soft materials.
Surface tension and surface energy are closely related, although not identical concepts. Surface tension is a generalized force; unlike a conventional mechanical force, it is not applied to any particular body or point. Using this notion, we suggest a simple geometric interpretation of the Young, Wenzel, Cassie, Antonoff and Girifalco–Good equations for the equilibrium during wetting. This approach extends the traditional concept of Neumann’s triangle. Substances are presented as points, while tensions are vectors connecting the points, and the equations and inequalities of wetting equilibrium obtain simple geometric meaning with the surface roughness effect interpreted as stretching of corresponding vectors; surface heterogeneity is their linear combination, and contact angle hysteresis is rotation. We discuss energy dissipation mechanisms during wetting due to contact angle hysteresis, the superhydrophobicity and the possible entropic nature of the surface tension.
The separation of motion technique provides insights on how vibro-levitation of droplets and soft materials including cornstarch is related with the vibro-stabilization of an inverted pendulum and the “Indian rope trick”.