Temperature affects elastic rock properties but is less-studied and thus less-understood than pressure and stress. Thermal effects on dispersion are experimentally observed herein from seismic to ultrasonic frequencies: Young’s moduli and Poisson’s ratios plus P- and S-wave velocities are determined by forced oscillation (FO) from 1 to 144 Hz and by pulse transmission at 500 kHz. Despite being the dominant sedimentary rock type, shales receive less experimental attention than sandstones and carbonates. To our knowledge, no other FO studies on shale at above ambient temperatures exist. Temperature fluctuations are enforced by two temperature cycles from 20 via 40 to 60 °C and vice versa. Measured rock properties are initially irreversible but become reversible with increasing number of heating and cooling segments. Rock property sensitivity to temperature is likewise reduced. It is revealed that dispersion shifts towards higher frequencies with increasing temperature (reversible if decreased), Young’s moduli and P-wave velocity maxima occur at 40 °C for frequencies below 56 Hz, and S-wave velocities remain unchanged with temperature (if the first heating segment is neglected) at seismic frequencies. In comparison, ultrasonic P- and S-wave velocities are found to decrease with increasing temperatures. Behavioural differences between seismic and ultrasonic properties are attributed to decreasing fluid viscosity with temperature. We hypothesize that our ultrasonic recordings coincide with the transition-phase separating the low- and high-frequency regimes while our seismic recordings are within the low-frequency regime.

Carbon capture and storage (CCS) by geological sequestration comprises a permeable formation (reservoir) for CO₂ storage topped by an impermeable formation (caprock). Time-lapse (4D) seismic is used to map CO₂ movement in the subsurface: CO₂ migration into the caprock might change its properties and thus impact its integrity. Simultaneous forced-oscillation and pulse-transmission measurements are combined to quantify Young’s modulus and Poisson’s ratio as well as P- and S-wave velocity changes in the absence and in the presence of CO₂ at constant seismic and ultrasonic frequencies. This combination is the laboratory proxy to 4D seismic because rock properties are monitored over time. It also improves the understanding of frequency-dependent (dispersive) properties needed for comparing in-situ and laboratory measurements. To verify our method, Draupne Shale is monitored during three consecutive fluid exposure phases. This shale appears to be resilient to CO₂ exposure as its integrity is neither compromised by notable Young’s modulus and Poisson’s ratio nor P- and S-wave velocity changes. No significant changes in Young’s modulus and Poisson’s ratio seismic dispersion are observed. This absence of notable changes in rock properties is attributed to Draupne being a calcite-poor shale resilient to acidic CO₂-bearing brine that may be a suitable candidate for CCS.