The tannery industry is one of the economic sectors that contributes to the development of different countries. Globally, Europe and Asia are the main producers of this industry, although Latin America and Africa have been growing considerably in recent years. With this growth, the negative environmental impacts towards different ecosystem resources as a result of the discharges of recalcitrated pollutants, have led to different investigations to generate alternative solutions. Worldwide, different technologies have been studied to address this problem, biological and physicochemical processes have been widely studied, presenting drawbacks with some recalcitrant compounds. This review provides a context on the different existing technologies for the treatment of tannery wastewater, analyzing the physicochemical composition of this liquid waste, the impact it generates on human health and ecosystems and the advances in the different existing technologies, focusing on advanced oxidation processes and the use of microalgae. The coupling of advanced oxidation processes with biological processes, mainly microalgae, is seen as a viable biotechnological strategy, not only for the removal of pollutants, but also to obtain value-added products with potential use in the biorefining of the biomass.

The use of pesticides in agriculture has ensured the production of different crops. However, pesticides have become an emerging public health problem for Latin American countries due to their excessive use, inadequate application, toxic characteristics, and minimal residue control. The current project evaluates the ability of two strains of algae (Chlorella and Scenedesmus sp.) and one cyanobacteria (Hapalosyphon sp.) to remove excess pesticides and other nutrients present in runoff water from rice production. Different concentrations of wastewater and carbon sources (Na₂CO₃ and NaHCO₃) were evaluated. According to the results, all three strains can be grown in wastewater without dilution (100%), with a biomass concentration comparable to a synthetic medium. All three strains significantly reduced the concentration of NO₃ and PO₄ (95 and 85%, respectively), with no difference between Na₂CO₃ or NaHCO₃. Finally, Chlorella sp. obtained the highest removal efficiency of the pesticide (Chlorpyrifos), followed by Scenedesmus and Hapalosyphon sp. (100, 75, and 50%, respectively). This work shows that it is possible to use this type of waste as an alternative source of nutrients to obtain biomass and metabolites of interest, such as lipids and carbohydrates, to produce biofuels.

The tanning industry transforms animal skins into leather and produces liquid effluents with a high organic and inorganic pollutant load. This work evaluated the effect of the tannery wastewater (TWW) concentration and the light/dark cycle on the production of biomass, carbohydrates, proteins, lipids, and pigments (carotenoids and phycobiliproteins) on two microalgae (Chlorella sp. and Scenedesmus sp.) and one cyanobacterium (Hapalosiphon sp.). A non-factorial central experimental design with a response surface was implemented using the STATISTICA 7.0 software. High removal percentages for nitrates (97%), phosphates (73.3%), and chemical oxygen demand (93.2%) were achieved with the three strains. The results also highlight that the use of a constant light regime (24:0) and the concentration of real TWW affect the biomass production, since the highest concentration of biomass recorded was 1.31 g L⁻¹ of Hapalosiphon sp. with 100% undiluted wastewater.

The textile industry is a global economic driving force; however, it is also one of the most polluting industries, with highly toxic effluents which are complex to treat due to the recalcitrant nature of some compounds present in these effluents. This research focuses on the removal of Chemical Oxygen Demand (COD), color, Total Organic Carbon (TOC), and Ammoniacal Nitrogen (N-NH₃) on tannery wastewater treatment through an advanced oxidation process (AOPs) using sodium bicarbonate (NaHCO₃), hydrogen peroxide (H₂O₂) and temperature using a central composite non-factorial design with a surface response using Statistica 7.0 software. All experiments used a 500 mL reactor with 300 mL of tannery wastewater from a company in Cúcuta, Colombia. The physicochemical characterization was done to determine the significant absorbance peaks about the color in the wavelengths between 297 and 669 nm. Statistical analysis found that the concentration of NaHCO₃ affects the removal of color and N-NH₃; however, it did not affect COD and TOC. The optimal process conditions for removing the different compounds under study were: NaHCO₃ 1 M, H₂O₂ 2 M, and 60 °C, with efficiencies of 92.35%, 31.93%, 68.85%, and 35.5% N-NH₃, COD, color, and TOC respectively. It can be concluded that AOPs using H₂O₂ and NaHCO₃ are recommended to remove color and N-NH₃.