This review article focuses on metal–organic framework (MOF) composites and the impact of mixing MOFs with other materials, such as polymers, carbon-based materials, and magnetic particles, to increase their performance to remove metals from water.

It is increasingly apparent that porous liquids (PLs) have unique use cases due to the combination of ready liquid handling and their inherently high adsorption capacity. Among the PL types, those with permanent porosity are the most promising. Although Type II and III PLs have economic synthetic methods and can be made from a huge variety of metal-organic frameworks (MOFs) and solvents, these nanocomposites still need to be stable to be useful. This work aims to systematically explore the possibilities of creating PLs using different MOF modification methods. This delivered underpinning insights into the molecular-level influence between solvent and MOF on the overall nanocomposite stability. Zirconium-based metal-organic frameworks were combined with two different solvents of varying chemistry to deliver CO₂ sorption capacities as high as 2.9 mmol g^-1 at 10 bar. The results of the study could have far-reaching ramifications for future investigations in the PL field.

Despite the known impacts on climate change of carbon dioxide emissions, the continued use of fossil fuels for energy generation leading to the emission of carbon dioxide (CO₂) into the atmosphere is evident. Therefore, innovation to address and reduce CO₂ emissions from industrial operations remains an urgent and crucial priority. A viable strategy in the area is postcombustion capture mainly through absorption by aqueous alkanolamines, which focuses on the separation of CO₂ from flue gas, despite its limitations. Within this context, porous materials, particularly metal-organic frameworks (MOFs), have arisen as favorable alternatives owing to their significant adsorption capacity, selectivity, and reduced regeneration energy demands. This research evaluates the engineering insights into tailored MOFs for enhanced CO₂ capture, focusing on three series of MOFs (ZIF, UiO-66, and BTC) to investigate the effects of organic ligands, functional groups, and metal ions. The evaluation encompassed a range of aspects including adsorption isotherms of pure gases [CO₂ and nitrogen (N₂)] and mixed gas mixture (CO₂ and N₂ with 15:85% ratio), along with utilization of the ideal adsorbed solution theory (IAST) to simulate multicomponent gas adsorption isotherms. Moreover, the reliability of IAST for mixed gas adsorption prediction has been investigated in detail. The research offers valuable insights into the correlation between the characteristics of MOFs and their effectiveness in gas separation and how these characteristics contribute to the differences between IAST predictions and experimental results. The findings enhance the understanding of how to enhance MOF characteristics in order to reduce CO₂ emissions and also highlight the need for advanced models that consider thermodynamic nonidealities to accurately predict the behavior of mixed gas adsorption in MOFs. As a result, the incorporation of MOFs with enhanced predictability and reliability into CO₂ capture industrial processes is facilitated.

Lead detection for biological environments, aqueous resources, and medicinal compounds, rely mainly on either utilizing bulky lab equipment such as ICP-OES or ready-made sensors, which are based on colorimetry with some limitations including selectivity and low interference. Remote, rapid and efficient detection of heavy metals in aqueous solutions at ppm and sub-ppm levels have faced significant challenges that requires novel compounds with such ability. Here, a UiO-66(Zr) metal-organic framework (MOF) functionalized with SO${}_3$H group (SO${}_3$H-UiO-66(Zr)) is deposited on the end-face of an optical fiber to detect lead cations (Pb${}^{2+}$) in water at 25.2, 43.5 and 64.0 ppm levels. The SO${}_3$H-UiO-66(Zr) system provides a Fabry–Perot sensor by which the lead ions are detected rapidly (milliseconds) at 25.2 ppm aqueous solution reflecting in the wavelength shifts in interference spectrum. The proposed removal mechanism is based on the adsorption of [Pb(OH${}_2$)${}_6$]${}^{2+}$ in water on SO${}_3$H-UiO-66(Zr) due to a strong affinity between functionalized MOF and lead. This is the first work that advances a multi-purpose optical fiber-coated functional MOF as an on-site remote chemical sensor for rapid detection of lead cations at extremely low concentrations in an aqueous system.

The purpose of this study was to design and develop a self-supporting glass MOF membrane (GMM) including its design, fabrication under different heat treatment temperatures, analysis of its physical–chemical properties, and assessment of its separation performance. Glass MOFs preserve metal–ligand bonding structures similar to their crystalline counterparts, providing intrinsic gas separation properties alongside the benefits of amorphous materials, including reduced grain boundaries and ease of processing. In this work, ZIF-62 was melted and then cooled to fabricate GMMs using vitrification to enhance molecular sieving. This study systematically examines the impact of varying thermal treatment temperatures (400–475 °C) on the physical and chemical transformations of GMMs, revealing their effects on the porosity, defect formation, and molecular sieving performance through advanced characterization techniques (e.g., solid-state nuclear magnetic resonance (13C NMR), X-ray photoelectron spectroscopy (XPS), He pycnometry, and positron annihilation lifetime spectroscopy (PALS)). The optimal GMM exhibits an impressive separation performance, particularly for H2 separation. The GMM at 4 bar and 25 °C exhibited He, H2, CO2, N2, and CH4 gas permeations of 576.37, 509.23, 146.07, 3.45, and 2.28 barrer, respectively. The ideal selectivities of H2/CH4, CO2/N2, CO2/CH4, H2/N2, and H2/CO2 gas pairs were 223.47, 42.37, 64.10, 147.71, and 3.49, respectively, which significantly exceed earlier reported values for ZIF-62 membranes, demonstrating the significant potential for GMMs as high-performance molecular sieve membranes, particularly for H2 separation. This work by optimizing the vitrification process through systematic temperature control highlights GMM’s ability to achieve high selectivity and permeability, positioning it as a promising candidate for industrial gas separation applications.