Lignocellulosic rice processing residue was pretreated in liquid hot water (LHW) at three different temperatures (140, 160, and 180 °C) and two pretreatment times (10 and 20 min) in order to assess its effects on hydrolysates composition, matrix structural changes and methane yield. The concentrations of acetic acid, 5-hydroxymethylfurfural and furfural increased with pretreatment severity (log Ro). The maximum methane yield (276 L kg⁻¹ VS) was achieved under pretreatment conditions of 180 °C for 20 min, with a 63% increase compared to untreated biomass. Structural changes resulted in a slight removal of silica on the upper portion of rice husks, visible predominantly at maximum severity. However, the outer epidermis was kept well organized. The results indicate, at severities 2.48 ≤ log Ro ≤ 3.66, a significant potential for the use of LHW to improve methane production from rice processing residue.

The present Cuban economic model focuses on renewable sources of energy production, according to sustainable development strategies for 2030. However, the strategies do not consider biogas (or methane) due to, among other reasons, a lack of knowledge of its actual potential. Following the methodology of the batch anaerobic digestion process, the study shows the biomethane potential contained in the most critical agricultural solid wastesgenerated in Cuba, i.e., rice straw, cane straw, corn straw, bean straw, banana straw (leaves), coffee husk, and parchment coffee. Biochemical Methane Potential (BMP) was assayed by lab-scale (585 ml) batch reactors, using the pig manure anaerobic sludge as inoculum under mesophilic conditions (35 ± 2 °C). Physicochemical parameters (total volatile solids, pH, alkalinity, volatile fatty acid concentration, and alkalinity ratio) were determined for processstability, quantifying the biogas production daily. Subsequently, the BMP was calculated for all substrates. The results showed that corn straw (0.42 l CH4 per gram of volatile solids) contained the highest biomethane potential. Stability on all systems was obtained, demonstrating the viability of the inoculum used to start digesters that treat this waste.The total potential methane obtained was 1258 106 m3/year, which is enough to generate 3,750 GWh of power per year—equivalent to 18 % of the total annual electricity generation in the country.