The presence of both microplastics and per- and polyfluoroalkyl substances (PFAS) is ubiquitous in the environment. The ecological impacts associated with their presence are still poorly understood, however, these contaminants are extremely persistent. Although plastic in the environment can concentrate pollutants, factors such as the type of plastic and duration of environmental exposure as it relates to the degree of adsorption have received far less attention. To address these knowledge gaps, experiments were carried out that examined the interactions of PFAS and microplastics in the field and in a controlled environment. For field experiments, we measured the abundance of PFAS on different polymer types of microplastics that were deployed in a lake for 1 month and 3 months. Based on these results, a controlled experiment was conducted to assess the adsorption properties of microplastics in the absence of associated inorganic and organic matter. The adsorption of PFAS was much greater on the field-incubated plastic than what was observed in the laboratory with plastic and water alone, 24 to 259 times versus one-seventh to one-fourth times background levels. These results suggest that adsorption of PFAS by microplastics is greatly enhanced by the presence of inorganic and/or organic matter associated with these materials in the environment, and could present an environmental hazard for aquatic biota.

We present an alternative ball milling system coupling BN, as catalyst, with activated carbon as a pre-concentration medium to destroy higher amounts of PFAS more efficiently.

Characterizing and enumerating microplastics (MPs) have received considerable attention in recent years. Most attention has focused on major waterways and especially in the water column. However, less is known about MPs in smaller lakes and tributaries, as well as in sediments, under both base flow and storm flow conditions. This study examines the role of an unnamed tributary in transporting microplastics and 6PPD-quinone from a major state highway into a small, salt-impacted, lake in Grand Rapids, Michigan. Water and sediment samples were collected over a one-year period to characterize microplastic types, abundances, and seasonal variability, while environmental conditions were monitored to assess storm event impacts. Results confirmed widespread microplastic presence in both habitats, with abundances ranging from 61–16,390 MPs/L. Many microplastics were black fragments, often unidentifiable but suspected to be rubber-derived. Storm events significantly increased microplastic transport, particularly in the tributary, where concentrations peaked at 16,390 /L during fall stormflow. 6-PPD-quinone concentrations were very low overall (<1 ng/L) with spikes during storm events in the tributary (up to 201 ng/L). Sediment analysis revealed higher microplastic abundances in the tributary compared to the lake, with black fragments dominating in both habitats. These findings underscore the critical role of storm-driven runoff in microplastic and chemical transport, highlighting the need for improved road infrastructure design to mitigate environmental impacts on downstream water bodies.

Characterizing and enumerating microplastics (MPs) have received considerable attention in recent years. Most attention has focused on major waterways and especially in the water column. However, less is known about MPs in smaller lakes and tributaries, as well as in sediments, under both baseflow and storm flow conditions. This study examines the role of an unnamed tributary in transporting microplastics and 6PPD-quinone from a major state highway into a small, salt-impacted lake in Grand Rapids, Michigan. Water and sediment samples were collected over a one-year period to characterize microplastic types, abundances, and seasonal variability, while environmental conditions were monitored to assess storm event impacts. Results confirmed widespread microplastic presence in both habitats, with abundances ranging from 61 to 16,390 MPs/L. Many microplastics were black fragments, often unidentifiable but suspected to be rubber-derived. Storm events significantly increased microplastic transport, particularly in the tributary, where concentrations peaked at 16,390/L during fall stormflow. Concentrations of 6-PPD-quinone were very low overall (<1 ng/L), with spikes during storm events in the tributary (up to 201 ng/L). Sediment analysis revealed higher microplastic abundances in the tributary compared to the lake, with black fragments dominating in both habitats. These findings underscore the critical role of storm-driven runoff in microplastic and chemical transport, highlighting the need for improved road infrastructure design to mitigate environmental impacts on downstream water bodies.