International audienceInformation is presented from high speed video imaging of the free surface of coatings being grown on aluminium substrates by PEO processing. The exposure time during image capture ranged down to 5.5 mu s, while the linear spatial resolution of the images ranged upwards from about 12 mu m. The area being viewed was about 2.4 mm(2), which was taken to be representative of the substrate area as a whole (similar to 129 mm(2)). PEO processing was carried out at 50 Hz AC. The periods over which image sequences were captured was about 100 ms, covering several cycles of variation of the applied potential. This operation was repeated periodically while the coating thickness increased from a few microns to several tens of microns. During the imaging periods, it was typically observed that tens or hundreds of individual discharges were occurring, all of them readily distinguishable from the background light levels. Their duration was of the order of several tens of microseconds. It was noticeable that they tended to occur in ``cascades'' at particular locations, each sequence comprising tens or hundreds of individual discharges, with an ``incubation'' period between them of the order of several hundreds of microseconds. It seems likely that they all occurred during the positive (anodic) half-cycle, while the applied voltage was sufficiently high. An individual cascade tended to persist (at the same location) over several voltage cycles. As the coating became thicker, these characteristics broadly persisted, although individual discharges became longer-lived and more energetic. An attempt is made to relate these observations to the overall picture of how coating growth takes place during PEO processing, and also to th

This review contains a theoretical background of optical emission spectroscopy and some selected examples of issues in the field of atmospheric plasmas. It includes elements like line broadening, emission of continua and molecules, radiation models, etc. Modernized expressions figuring the terms hidden in global constants where cgs units prevail are given together with restrictions of use. Easy-to-use formulas are provided to give access to essential plasma parameters.