We present direct observation of the velocity-selective optical pumping of the Rb ground state hyperfine levels induced by $5S_{1/2}\to 5P_{1/2}$ femtosecond pulse-train excitation. A modified direct frequency comb spectroscopy based on the fixed frequency comb and a weak cw scanning probe laser was developed. The femtosecond pulse-train excitation of a Doppler-broadened Rb four-level atomic vapor is investigated theoretically in the context of the density matrix formalism and the results are compared with the experiment.

A mode-locked femtosecond laser is used to physically map the laser frequency comb into the velocity comb of the excited Rb atoms at room temperature. Upon resonant excitation by discrete optical frequencies the velocity distribution of the excited Rb atoms shows comblike structure. Simultaneously, velocity-selective population transfer occurs between ground-state hyperfine levels. Both facts are observed by modified direct frequency comb spectroscopy and verified by a detailed density matrix treatment of the multilevel system in resonant field.

In this work we investigate operation in the Geiger mode of the new single photon avalanche photo diode (SPAD) SAP500 manufactured by Laser Components. This SPAD is sensitive in the range 400-1000nm and has a conventional reach-through structure which ensures good quantum efficiency at the long end of the spectrum. By use of passive and active quenching schemes we investigate detection efficiency, timing jitter, dark counts, afterpulsing, gain and other important parameters and compare them to the “standard” low noise SPAD C30902SH from Perkin Elmer. We conclude that SAP500 offers better combination of detection efficiency, low noise and timing precision.