The recovery of iron, chromium, and nickel from stainless steel dust (SSD) has attracted considerable attention for their utilization as secondary resources in the ever-growing field of steelmaking. This paper investigates the reduction process of SSD briquettes in iron-baths in detail in order to determine the optimum processing parameters. A novel method of analysis by studying the erosion behavior of a corundum crucible was adopted to accurately calculate the recovery rate of the metals, and the effect of the parameters on the triple metals recovery rate was determined by orthogonal testing. The results show that the most important factor for the SSD briquetting process is water, followed by sucrose, carbon, and pressure. The optimum parameters of the SSD briquetting process are 13 wt% sucrose, 13 wt% water, 11 wt% carbon, and 30 MPa pressure. The compressive intensity was found to be 27.6 MPa. When a basicity of 1.6, 17% carbon, 5 wt% ferrosilicon, and 6% CaF 2 were used in the SSD briquette reduction process, the triple metal recovery rate was in the range of 94 –100 %, 90 –100 %, and almost 100 %, respectively.
1 October 2020 in Science of The Total Environment
Carbon monoxide is the major hazardous component in flue gas exhausting from the iron ore sintering. This study aims to reduce the CO emission by changing the sinter parameters by sintering pot tests; specifically, the sinter quality, CO concentration, and total emission in sintering flue gas were analyzed in detail. The sinter strength properties, including the shatter index and the tumble index, are analyzed by the sintering pot test and the sintering flue gas discussion. The results show that the CO emission can be suppressed by modifying the sinter parameters, such as carbon content, coke breeze and coal breeze ratio, water addition, and sintering negative pressure. The good sinter parameters with the lower CO emission are 2.8% carbon content and 7.5% water in the sintering mixture. A higher coke breeze to coal breeze ratio, or only coke breeze fuel in the sinter mixture, is beneficial for the lower CO emission with a negative fan pressure of −12 kPa.
Mineralogical phases of steelmaking slags have significant influences on the carbonation of the slags. In this paper, the effects of temperature and reaction time on the conversion of calcium-related phases and the carbonation degree of a slag sample were studied. The experimental conditions were a liquid-to-solid ratio of 20 mL/g, a carbon dioxide flow rate of 1 L/min and a slag particle size of 38–75 μm. The results show that the optimum carbonation temperature and reaction time are 60 °C and 90 min, respectively, and calcite phase content is about 26.78% while the conversion rates of Ca3Al2O6, CaSiO3, Ca2SiO4 and free CaO are about 40%, 42.46%, 51% and 100%, respectively, and the carbon dioxide sequestration efficiency is about 170 g/kg slag.
18 March 2022 in Metallurgical and Materials Transactions B