Sustainability and waste management on board are key issues that need to be addressed by the maritime sector also in terms of greenhouse gas emissions (GHG). With the aim of evaluating waste management alternatives in a circular economy perspective, the study examines a combined system for the optimisation of ship waste management and assesses its possible use for energy purposes. Different systems are analysed in relation to their GHG emission reduction potential regardless of routes and ports of destination. A SWOT (Strengths, Weaknesses, Opportunities and Threats) analysis was carried out on waste management alternatives in order to preliminary identify their potential in terms of GHG emissions reduction, cost, environmental sustainability, methodological coherence, feasibility and replicability. Following this analysis, two case studies of particular interest were identified: (1) the thermo-chemical treatment of waste oils and sludge to obtain fuel oils; (2) the installation of a waste-to-energy plant and subsequent energy recovery on board. UNFCCC (United Nations Framework Convention on Climate Change) methodologies were applied to these two case studies to calculate GHG emission reduction resulting from their implementation. The obtained results are presented with the aim of supporting sustainable waste management strategies on board in a circular carbon economy perspective.
Mass transfer phenomena in polymeric electrolyte membrane fuel cells (PEMFC) electrodes has already been analyzed in terms of the interactions between diffusive and forced flows. It was demonstrated that the whole phenomenon could be summarized by expressing the Sherwood number as a function of the Peclet number. The dependence of Sherwood number on Peclet one Sh(Pe) function, which was initially deduced by determining three different flow regimes, has now been given a more accurate description. A comparison between the approximate and the accurate results for a reference condition of diluted reactant and limit current has shown that the former are useful for rapid, preliminary calculations. However, a more precise and reliable estimation of the Sherwood number is worth attention, as it provides a detailed description of the electrochemical kinetics and allows a reliable comparison of the various geometrical arrangements used for the distribution of the reactants.