Polymer composites are materials that are used in many industries. Their wide application has a direct impact on the amount of post-production and post-consumer waste. The global problem with recycling, especially of fiber-reinforced polymeric materials, has prompted research into methods of their use. Previous research on composite materials with polyester–glass recyclate showed a decrease in mechanical properties. The construction material should have the highest mechanical properties. Based on the literature, it was found that the use of nanoadditives may have a positive effect on the parameters of the materials. The use of gamma aluminum nanopowder, in a small amount can significantly increase the mechanical properties of composites with polyester–glass recyclate, and thus can affect the application of these materials to structural elements. The article is devoted to the research on the hardness of composite materials with polyester–glass recyclate and gamma aluminum nanopowder. The main goal is to investigate the possibility of using a nanoadditive as a material, increasing the mechanical properties of composites with polyester–glass recyclate, so as to create a recycled material with the highest possible strength parameters. Hardness tests were performed using the Barcol method. For each composite material, 30 measurements were made in order to subject the results to a statistical analysis. Using parametric statistical tests it was shown that the obtained hardness values at the assumed level of statistical significance pv = 0.05 for comparisons for the samples of the reference material (B0) do not differ by chance, while for the comparisons in the configurations of the reference material (B0) with the modified materials, (R10, A2, R10A2) they do not differ by accident. Studies have shown that the addition of 2% gamma aluminum nanopowder slightly lowers the hardness of a pure polyester–glass composite, but the same additive allows the hardness of composite materials to be increased with the addition of glass recyclate. This is of particular importance for the development of the optimal composition of polyester–glass composites with the addition of recyclate, which will have good strength properties and at the same time enable the reuse of composite waste.
The article presents a method of modifying the strength properties of epoxy–glass composite by changing the percentage composition of the matrix by the addition of rubber recyclate. Taking into account environmental protection and economic conditions in the process of recycling and utilisation of waste, it is advisable to look for applications of non-degradable waste materials. Based on epoxy resin, a glass mat with a random direction of fibres and rubber recyclate, a test material with different percentage compositions was produced. Samples from the manufactured materials were subjected to a static tensile test on a ZwickRoell testing machine using the ARAMIS SRX measuring system. In addition, CT (computerized tomography) scans of the inside of the samples were made using a ZEISS METROTOM 6 Scout tomograph, and observations of the internal structures were made using a scanning electron microscope. The use of optical and microscopic techniques enabled the precise determination of strength parameters of the examined composites and the analysis of the behaviour of samples under load. The analysis of deformations over time in the examined samples showed a beneficial effect of the addition of rubber recyclate on the elastic properties of the examined composites.
1 April 2023 in Journal of Achievements in Materials and Manufacturing Engineering
The article presents a statistical analysis of strength parameters of newly developed epoxy-glass composite materials modified with the addition of rubber recyclate.Three variants of materials with a percentage of recyclate content in the composite matrix of 3%, 5%, 7% and a reference variant without the addition of recyclate were used for the study. The samples were subjected to an impact test on a ZWICK RKP 450IR-GE impact hammer. Resilience measurement values were subjected to statistical analyses at the significance level = 95%, such as: testing the normality of distributions with the Shapiro-Wilk test, testing differences between pairs with the Student's t-test for dependent groups, and testing ANOVA differences for independent groups.The Shapiro-Wilk test confirmed that the resilience variables for all tested samples were in normal distributions; therefore the highest power parametric tests were used to test the differences. Using the Student's t-test, it was confirmed that between pairs of variables in configurations: standard sample with the modified sample, there were significant statistical differences in the distribution of resilience values for all samples. ANOVA confirmed significant changes in impact strength in 10 comparison variants.The obtained test results showed that in 9 compared cases, there were significant statistical differences, and in one case, there were no significant differences.The performed statistical analyses confirmed their significant usefulness in the process of qualification of strength parameters for materials with high anisotropy, such as composites.The manufactured products are innovative in terms of the method of using the addition of rubber recyclate as a filler for epoxy-glass composites. The use of static methods for their study also has practical value. It optimizes the analysis methods of the results of measurements of strength parameters of new composite materials.
Currently, there is a noticeable trend of modifying new materials by using additives from the recycling of harmful waste. This is to protect the environment by using waste to produce composites and at the same time to reduce the cost of their production. The article presents an analysis of the impact of the use of rubber recyclate obtained from the utilization of car tires as a sandwich layer of epoxy–glass composites and its impact on the strength parameters of the composite. The presented research is an extension of the previously conducted analyses on composite materials modified with the addition of rubber recyclate. The four variants of the materials produced contained the same percentage amount of rubber recyclate, but differed in the way it was distributed and the number of layers. Static tensile tests as well as impact strength and kinetics of damage to samples made with and without the addition of recyclate were carried out. Observation of the structures of the materials with the use of SEM was also performed. A significant influence of the method of distributing the recyclate in layers on the strength parameters of the materials was found. In the case of composites with three and two sandwich layers of recyclate, more favorable results were obtained compared to the blank sample. In addition, the values of the impact strength measurements were subjected to statistical analysis at the significance level of α = 95%. The distributions were tested for normality with the Shapiro–Wilk test, differences between pairs were tested with the Student’s t-test for dependent groups, and ANOVA differences were tested for independent groups. Using the Student’s t-test, it was confirmed that between the pairs of variables in the configurations reference sample and modified sample, there were significant statistical differences in the distribution of impact strength measurement results for all the analyzed materials. Statistical analysis showed a significant usefulness in the selection of the material with the best strength parameters and a significant role of statistical methods in the study of anisotropic materials.
This paper investigates the structure and mechanical characteristics of a coating based on an AlSi12 alloy, obtained by centrifugal induction surfacing as an alternative to a bronze sliding bearing. To provide for the adhesion of an aluminum layer to the inner surface of a steel bearing housing, a sublayer of low-melting metals was formed, while the formation of the main layer and the sublayer was done in a single processing cycle. The low-melting metals had higher density, which ensured that the sublayer was created at the interface with the steel bearing housing under the action of centrifugal forces. It is shown that the low-melting sublayer forms a strong bond both with the aluminum alloy and with the steel base. Lead and tin are used as low-melting additives. It has been established that lead or tin used in a sublayer are indirectly involved in the structural formation of boundary layers of steel and aluminum claddings, acting as a medium for diffuse mass transfer. Thus, lead is not included in the composition of the main coating and does not change the chemical composition of the aluminum layer. After the addition of tin, the aluminum develops a dendritic structure, with tin captured in the interdendritic space. In this case, the deposited layer is saturated with iron with the formation of intermetallic (Fe, Al, Si) compounds, both at the interface and in the coating volume. This paper offers an explanation of the mechanism through which Pb and Sn act on the structure formation of the coating, and on the boundary layer of the steel bearing housing. Tribological tests have shown that the resulting materials are a promising option for plain bearings and highly competitive with the CuSn10P bronze.
1 January 2021 in Science and Engineering of Composite Materials
Composite materials are used in many industries. Their mechanical and physical properties as well as their low weight make them suitable for use in many constructions. Their wide application generates a problem with their disposal. Therefore, it is necessary to design new materials based on waste from polyester–glass laminates in order to introduce a closed circuit in the composite production process. The article presents research aimed at determining solid material composites with polyester–glass recyclate, in order to use these materials for modeling the structure. The aim of this study was to determine the effect of the addition of recyclate to the polyester–glass composite on the deformation and the value of the Poisson number of the material. During the study, samples from composites with the addition of polyester–glass recyclate were used. Samples made in accordance with the standard for plastics PN-EN ISO 527-4_2000P were subjected to static tensile test on a universal testing machine, with variable load parameters. During the test, the longitudinal and transverse elongations of the samples were measured using a strain gauge measuring system. On the basis of the measurements, the values of Poisson numbers were determined, which allowed for a preliminary assessment of the impact of the recyclate content in the composite on its deformability.