We report on stimulated emission at wavelengths up to 19.5 μm from HgTe/HgCdTe quantum well heterostructures with wide‐gap HgCdTe dielectric waveguide, grown by molecular beam epitaxy on GaAs(013) substrates. The mitigation of Auger processes in structures under study is exemplified, and the promising routes towards the 20–50 μm wavelength range, where HgCdTe lasers may be competitive to the prominent emitters, are discussed.

Photoluminescence (PL) and photoconductivity (PC) studies of Hg_1−xCd_xTe (0.19 ≤ x ≤ 0.23) epitaxial films are presented. Interband PL is observed at wavelengths from 26 to 6 μm and in the temperature range 18 K–200 K. The PL line full width at half maximum is about 6 meV (4kT) at 18 K and approaches its theoretical limit of 1.8kT at higher temperatures. Carrier recombination process is also investigated by time resolved studies of PL and PC at pulsed excitation. Radiative transitions are shown to be the dominating mechanism of carrier recombination at high excitation levels.

Carrier lifetimes in the continuum of the quantum well of a Hg _x Cd_{1 − x} Te/Cd _y Hg_{1 − y} Te hetero-structure were studied by terahertz pump-probe spectroscopy. It is found that the relaxation duration of the transmission signal is ∼65 ps and is independent of the pump power. Such rapid relaxation in these structures is most likely determined by the interaction of holes with acoustic phonons due to a high density of states in the valence band and a larger effective mass compared with electrons. By the obtained data, the times of the interband nonradiative recombination of holes are determined. In this publication, we report the results of numerical calculation of the energy spectrum of the model structure, in which the possibility of obtaining population inversion at specified concentrations of nonequilibrium carriers is analyzed.

Investigation into far infrared photoconductivity (PC) in narrow-gap epitaxial bulk Hg1–xCdxTe (x < 0.2) films grown by molecular beam epitaxy and chemical vapor deposition techniques is presented. A broadband of photosensitivity in terahertz region is found at 4.2 and 77 K. Some long-wavelength peculiarities of spectra are discovered and their origins are discussed. We also study PC relaxation process with nanosecond time resolution. It is found that carrier relaxation is non-radiative and measured lifetimes show that some of the structures are applicable for detecting in very long-wavelength infrared range.

The energy spectra of quantum-well narrow-bandgap Hg_{1 − y} Cd _y Te/Cd _x Hg_{1 − x} Te heterostructures have been studied. The dependences of the effective cyclotron mass on the density (in classical magnetic fields) and the transition energy (in quantizing fields) have been obtained from the cyclotron resonance measurements. These dependences confirm the near-linear dispersion law for the electrons with small mass at the band bottom (the minimum cyclotron mass measured is 0.003 m ₀). The interband photoconductivity of the CdHgTe-based structures with the long-wavelength photoresponse edge lower than 6 meV has been demonstrated.