From the viewpoint of green chemistry and sustainable development, it is of great significance to synthesize chemicals from CO₂ as C₁ source through C-N bond formation. During the past several decade years, many studies on C-N bond formation reaction were involved, and many efforts have been made on the theory. Nevertheless, several great challenges such as thermodynamic limitation, low catalytic efficiency and selectivity, and high pressure etc. are still suffered. Herein, recent advances are highlighted on the development of catalytic methods for chemical fixation of CO₂ to various chemicals through C-N bond formation. Meanwhile, the catalytic systems (metal and metal-free catalysis), strategies and catalytic mechanism are summarized and discussed in detail. Besides, this review also covers some novel synthetic strategies to urethanes based on amines and CO₂. Finally, the regulatory strategies on functionalization of CO₂ for N-methylation/N-formylation of amines with phenylsilane and heterogeneous catalysis N-methylation of amines with CO₂ and H₂ are emphasized.

It is promising and challenging to achieve the effective construction of carbonates using CO₂ and a non-noble metal catalyst. Herein, selective catalytic conversion of CO₂ and switchable alcohol candidates to produce linear or cyclic carbonates and α-hydroxy ketones via effective zinc catalyst was developed. A series of primary alcohols and cyclohexanol, 1,2-diols, and water can serve as nucleophiles to give alkyl or aryl 2-substituted-3-oxobutan-2-yl carbonates, substituted 1,3-dioxolan-2-ones, 3-substituted 3-hydroxybutan-2-ones, respectively with excellent selectivity and high yields.

Ni/Al₂O₃ catalyst prepared by combustion method was applied in a slurry methanation reaction to study the catalytic performance, especially the regeneration performance. The catalyst properties were characterized by (X-Ray diffraction) XRD, Inductively coupled plasma atomic emission spectrometer (ICP-AES), Nitrogen adsorption-desorption, Transmission electron microscopy (TEM), Thermogravimetric analysis (TG/DTG), Temperature programmed oxidation (TPO), and H₂ chemisorption before and after reaction. The results show that the catalyst deactivation was mainly due to carbon deposition, which exhibited amorphous carbon films and formed by the disproportionation of CO. The carbon deposition was formed on the catalyst surface and existed as carbon films during the reaction, then it gradually separated from the catalyst surface, generated an overlapping multi-layer three-dimensional carbon structure, which covered the active site and blocked the pores. As a result, the metal surface area of catalyst decreases, as well as the activity. The carbon deposition could be removed by oxidative calcination without destroying the catalyst structure, the active sites could be re-exposed and the catalyst activity could be recovered.

A systematic study of the comparative performances of different metal-impregnated HZSM-5 catalysts (Zn, Ga, Mo, Co, and Zr) for propane conversion is presented. The physicochemical properties of catalysts were characterized by means of XRD, BET, SEM, TEM, FTIR, XPS, ²⁷Al MAS NMR, NH₃-TPD and Py-FTIR. It was found that the acidities of the catalysts were significantly influenced by loading metal. More specifically, Mo-, Co- or Zr-modified catalysts showed a large metal size and low acidic density, resulting high olefin selectivity, while Zn- or Ga-modified catalysts maintained their small metal size and acidic density, and mainly reduced B/L due to the Lewis acid sites created by Zn or Ga species, resulting in high aromatics selectivity. Experimental results also showed that there is a balance between metals size and medium and strong acidity on propane conversion. Moreover, based on the different acidity of metal-modified HZSM-5 catalysts, the mechanism of propane conversion was also discussed.

The supporting modes of active metal over mesoporous materials play an important role in catalytic performance. The location of Ni nanoparticles inside or outside the mesoporous channel of MCM-41 has a significant influence on the reactivity in partial oxidation of methane to syngas reaction. The characterization data using different techniques (Transmission Electron Microscope (TEM), X-Ray Diffraction (XRD), N₂ adsorption-desorption, H₂ Temperature-Programmed Reduction (H₂-TPR), and Inductively Coupled Plasma (ICP)) indicated that nickel was located outside the mesoporous channels for the impregnation method (Ni/MCM-41), while nickel was encapsulated within MCM-41 via the one-step hydrothermal crystallization method (Ni-MCM-41). The nickel atoms were mainly dispersed predominantly inside the skeleton of zeolite. When the load amount of Ni increased, both of Ni species inside the skeleton or pore channel of zeolite increased, and the ordered structure of MCM-41 was destroyed gradually. Contributed by the strong interaction with MCM-41, the Ni particles of Ni-MCM-41 were highly dispersed with smaller particle size compared with supported Ni/MCM-41 catalyst. The Ni-MCM-41 displayed higher catalytic performance than Ni/MCM-41, especially 10% Ni-MCM-41 due to high dispersity of Ni. The confinement effect of MCM-41 zeolite also afforded high resistance of sintering and coking for 10% Ni-MCM-41 catalyst. Especially, 10% Ni-MCM-41 catalyst showed outstanding catalytic stability.

Highlighted elements are the feasible E atoms of CB ₃ E ₂ ^q template ppC structures, in which CB ₃ Mg ₂ ⁻ is suitable for photoelectron spectroscopy.