Europe’s low-carbon energy policy favors a greater use of fuel cells and technologies based on hydrogen used as a fuel. Hydrogen delivered at the hydrogen refueling station must be compliant with requirements stated in different standards. Currently, the quality control process is performed by offline analysis of the hydrogen fuel. It is, however, beneficial to continuously monitor at least some of the contaminants onsite using chemical sensors. For hydrogen quality control with regard to contaminants, high sensitivity, integration parameters, and low cost are the most important requirements. In this study, we have reviewed the existing sensor technologies to detect contaminants in hydrogen, then discussed the implementation of sensors at a hydrogen refueling stations, described the state-of-art in protocols to perform assessment of these sensor technologies, and, finally, identified the gaps and needs in these areas. It was clear that sensors are not yet commercially available for all gaseous contaminants mentioned in ISO14687:2019. The development of standardized testing protocols is required to go hand in hand with the development of chemical sensors for this application following a similar approach to the one undertaken for air sensors.
Microorganisms settle in diverse partially saturated porous media in the form of biofilms. The alteration of hydraulic properties and diffusive transport processes occurs simultaneously with biofilm growth in porous media. Imaging methods offer the ability to directly visualize and quantify alterations on the pore scale. However, imaging methods have mainly observed biofilm growth in completely saturated porous media. The current study used magnetic resonance imaging (MRI) to dynamically visualize biofilm growth within a porous medium under alternating drainage and flushing events. Prior to the MRI experiments, the sample was cultivated for 6 days within a porous medium consisting of 2 mm glass spheres. Starting from day 6, growth was monitored using MRI over a period of 7 days. The approach allowed for a visualization of all fractions (biofilm, water, air, and porous material) after drainage as well as flushing events. Biofilm was found to preferentially grow within permanently wetted areas situated next to pore throats. Furthermore, an increase in the water retention and connectivity of the liquid phase was found. The largest liquid cluster covered 11% (day 6) and 91% (day 12) of the total retained water, suggesting that biofilm growth might improve diffusive transport processes within partially saturated porous media.