Activated carbon (AC) was modified by FeCl₃. Batch experiments were carried out to evaluate the characteristics of equilibrium, kinetics and thermodynamics of Sulfamethazine adsorption onto original and modified AC. The results showed that Fe³⁺treatment changed the surface area, pore volume and surface zeta potential and increased the number of surface oxygenic functional groups. The adsorption of Sulfamethazine on modified activated carbon (MAC) was significantly improved. Isotherm test results revealed that the adsorption isotherms of Sulfamethazine on MAC fit the Freundlich, Langmuir and Temkin equations well. The maximum adsorption quantity of Sulfamethazine on MAC was 17.2414 mg/g at 25 °C. The adsorption kinetics of Sulfamethazine on AC and MAC can be characterized by the pseudo-second-order model. The adsorption process was affected by membrane diffusion, surface adsorption and internal diffusion. The adsorption quantities of Sulfamethazine first increased and then decreased for pH between 3 and 10. The removal efficiencies decreased with increasing temperature, which is favorable for adsorption at low temperature. It was also found that the mechanisms of adsorption included micropore capture and electrostatic, hydrogen bonding, π-π electron donor-acceptor (EDA) and coordination interactions as well as other interactions.

To enhance the photocatalytic activity of TiO₂, poly-2-aminobenzene sulfonic acid (P2ABSA)-modified TiO₂ nanocomposites were successfully synthesized using an in situ oxidative polymerization method. The modified nanocomposites were characterized by scanning electron microscopy, X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, UV-vis diffuse reflectance spectroscopy, and a photocurrent test. The photocatalytic degradation of methylene blue was chosen as a model reaction to evaluate the photocatalytic activities of TiO₂ and P2ABSA/TiO₂ nanocomposites, with results indicating that P2ABSA/TiO₂ exhibited the higher activity. The apparent first-order rate constant, k_app, of P/T(2/1) was 0.0138 min⁻¹, which was six times higher than that of TiO₂ (0.0021 min⁻¹). Meanwhile, the P2ABSA/TiO₂ nanocomposites showed excellent photocatalytic stability, which was dependent on structural stability. A photocatalytic activity enhanced mechanism has been proposed, accounting for the photosensitization effect and synergetic effect of TiO₂ with P2ABSA. Mass spectroscopy analysis showed that there were two possible degradation pathways for MB, via degradation of the chromophoric group or the auxochrome group.

Poly-o-phenylenediamine modified TiO₂ nanocomposites were successfully synthesized via an ‘in situ’ oxidative polymerization method. The modified nanocomposites were characterized by BET, XRD, TEM, FT-IR, TGA, XPS, EA and UV-Vis DRS. The photocatalytic degradation of methylene blue was chosen as a model reaction to evaluate the photocatalytic activities of TiO₂ and PoPD/TiO₂. The results indicated that PoPD/TiO₂ nanocomposites exhibited good photocatalytic activity and stability. The photocatalytic activity of PoPD/TiO₂ increased as the initial pH increased because of electrostatic adsorption between the photocatalyst and MB as well as the generation of ·OH, whereas it exhibited an earlier increasing and later decreasing trend as the concentration of the photocatalyst increased owing to the absorption of visible light. The photocatalytic stability of the PoPD/TiO₂ nanocomposite was dependent on the stability of its structure. Based on radical trapping experiments and ESR measurements, the origin of oxidizing ability of PoPD/TiO₂ nanocomposites on photocatalytic degradation of MB was proposed, which taking into account of ·OH and ·O₂⁻ were the first and second important ROS, respectively. The possible photocatalytic mechanism and photocatalytic activity enhanced mechanism has been proposed, taking into account the photosensitization effect and synergetic effect of TiO₂ with PoPD.

MIL-101(Fe)-based catalysts have been widely used for degradation of organic pollutants based on peroxymonosulfate (PMS) activation. Hence, a facile calcination and hydrothermal method was used in this study to prepare a MIL-101(Fe)/g-C₃N₄ composite catalyst with high activity and high stability for PMS activation to degrade tetracycline hydrochloride (TC) under visible-light irradiation. We clearly elucidated the mechanism involved in the MIL-101(Fe)/g-C₃N₄ photo Fenton-catalyzed PMS activation process by separating the PMS activation and pollutant oxidation processes. The synergetic effects of MIL-101(Fe) and g-C₃N₄ involved MIL-101(Fe) acting as an electron shuttle mediating electron transfer from the organic substrate to PMS, accompanied by redox cycling of the surface Fe(II)/Fe(III). Multiple experimental results indicated that PMS was bound to the surface of MIL-101(Fe)/g-C₃N₄ during visible irradiation and generation of sulfate radicals (SO₄^•-), hydroxyl radicals (•OH) and superoxide anion free radicals (•O₂^-) for the radical pathway and singlet oxygen (¹O₂) and holes (h⁺) for the nonradical pathway. The major degradation pathways for TC can be described as demethylation, deamination, deamidation and carbonylation. This work provides valuable information and advances the fundamental understanding needed for design and syntheses of metal-free conjugated polymers modified by metal-organic frameworks for heterogeneous photo-Fenton reactions.

The photocatalytic degradation of organic pollutants is an effective method of controlling environmental pollution. ZnO nanoparticles (ZnO NPs) were prepared by the solvothermal method and characterized by scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and UV–visible diffuse reflectance spectroscopy (UV–Vis DRS). The results showed that the ZnO NPs had a uniform size of 25–40 nm, hexagonal wurtzite structure, and a band gap of 2.99 eV. The photocatalytic degradation of methyl orange (MO) and p-nitrophenol (PNP) was used as a model reaction to evaluate the photocatalytic activity of ZnO NPs. The photocatalytic degradation rates (pseudo-first-order kinetics) of MO and PNP were 92% (0.0128 min⁻¹) and 56.2% (0.0042 min⁻¹), respectively, with a 25 W ultraviolet lamp, MO/PNP concentration = 20 mg/L, ZnO NPs dose = 1.5 g/L, and time = 180 min. The photocatalytic mechanism of ZnO NPs and degradation pathways of MO and PNP were also proposed. The results provide valuable information and guidance for the treatment of wastewater via photocatalytic methods.