Two-dimensional (2D) metal–organic frameworks have exhibited a range of fascinating attributes, of interest to numerous fields. Here, a calcium-based metal-organic framework with a 2D layered structure has been designed. Dual emissions relating to intralayer excimers and interlayer trapped excitons are produced, showing excitation-dependent shifting tendency, characteristic of a low dimensional semiconductor nature. Furthermore, the layer stacking by weak van der Waals forces among dynamically coordinated DMF molecules enables exfoliation and morphology transformation, which can be achieved by ultrasound in different ratios of DMF/H₂O solvents, or grinding under appropriate humidity conditions, leading to nano samples including ultrathin nanosheets with single or few coordination layers. The cutting down of layer numbers engenders suppression of interlayer exciton-related emission, resulting in modulation of the overall emitting color and optical memory states. This provides a rare prototypical model with switchable dual-channel emissions based on 2D-MOFs, in which the interlayer excitation channel can be reversibly tuned on/off by top-down exfoliation and morphology transformation.

Four Ru/Rh half-sandwich units are incorporated into UiO-67 frameworks by post-synthetic exchange (PSE) method, and employed for photocatalytic H₂ evolution and CO₂ reduction.

A new luminescent Eu-MOF from an amino-group modified tetracarboxylic acid ligand was designed, which could perform as an efficient pH acidity and Cd²⁺ PL sensor and CO₂ selector.