Purple soil is a type of global soil that is referred to by various names in different countries, which makes it difficult to understand, utilize, and ameliorate purple soil internationally. Soil Taxonomy (ST) and the World Reference Base for Soil Resources (WRB) are the most widely used soil classification systems in the world. The aim of this study was to clarify the classification of purple soil in ST and the WRB and to establish a reference between different classification systems of purple soil. Therefore, based on the current principles and methods of the ST and WRB systems, 18 typical purple soil profiles in the eastern Sichuan Basin were identified, retrieved, and classified. Then, the soil units of the WRB were compared with those of ST and the Chinese Soil Taxonomy (CST). The results revealed that the 18 typical purple soil profiles could be classified into three soil orders, four soil group orders, and seven soil subgroups in ST and four reference soil groups (RSGs) in the WRB; each profile had its own unique principal and supplementary qualifier combinations within the soil units. It was found that when compared with the ST system, the WRB and CST systems had stronger abilities to distinguish purple soil. In addition, the WRB system was able to more comprehensively consider soil characteristics such as soil layer thickness, ferric horizon, soil color, texture mutations, and carbonate through qualifiers. However, the CST system added diagnostic characteristics, such as the lithologic characteristics of purplish sandstones and shales and the ferric properties and alic properties at the soil group and subgroup levels, which enhanced the differentiation ability of the purple soil at the subgroup level.

Revealing the pedogenesis of soil on carbonate rocks is a key step in determining the boundaries of soil types along a climosequence. However, related research is lacking for a subtropical mountain. In this study, eight pedons were sampled across an elevation gradient (789–2322 m) having large variation in mean annual precipitation (MAP) (1189–1764 mm) and mean annual temperature (MAT) (5.7–14.9 °C). General processes were performed, including physical, chemical, and morphological characterizations, X-ray diffraction (XRD), total elements’ content, and soil classification of the carbonate rock. In the climo-toposequence, the illite had been transformed into illite-smectite below 1300–1500 m of elevation, 1300–1370 mm of MAP, and above 10.5–11.5 °C of MAT, and into vermiculite above this climate. These findings indicated that the effects of temperature on soil mineral transformation had weakened with the gradual increases in elevation. The pedon at 861 m of elevation, 1206 mm of MAP, and 14.5 °C of MAT, which accounted for the argic horizons, was divided into Argosols after human activities. The finding revealed that changes from forest to cultivated land could potentially accelerate the formation of argic horizons, and it provided a theoretical basis for global carbonate rocks’ weathering conditions and ecological problems in subtropical mountains. When the soils reached approximately 1100–1200 m of elevation, 1250–1300 mm of MAP, and 11.5–13.5 °C of MAT, the argic horizons of the soil could be accounted for, as evolved from the Cambosols in Chinese Soil Taxonomy (CST) (Inceptisols in Soil Taxonomy (ST), Cambisols in the World Reference Base for Soil Resources (WRB)) to the Argosols in CST (Alfisols in ST, Luvisols or Alisols in WRB) under natural vegetation. Therefore, it was indicated that the soil types changed significantly in the CST, ST, and WRB with increases of MAP and decreases of MAT, which provides a reference for determining the boundaries of the soil types along a climosequence in subtropical mountains.

It is of great significance to determine soil aggregate stability in predicting agricultural production conditions and soil erosion risk. However, the problem exposed in the process of evaluating soil aggregate stability cannot be ignored: Can the effects of different mechanisms on the degree of soil aggregate breakdown be distinguished by selecting ethanol and water as dispersion media? Based on this question, natural soils with a gradient in soil textures of silty loam to loamy clay were used as the test materials. Deionized water, ethanol and hexane were employed as soaking solutions to quantitatively analyze the extent to which the aggregates were dispersed in static disintegration experiments. The results suggested that the soil hydrophilicity (SH) of six soils with a texture gradient were >1 by comparing the aggregate breakdown index (ABI) of soils undergoing ethanol and hexane dispersion. This indicated that the hydrophilic group (-OH) contained in ethanol interacted with the hydrophilic surfaces of the soil particles. Therefore, the soil hydrophilicity (hydration) should be determined by comparing the ABI values undergoing hexane and water dispersion. From silty loam to loamy clay, the average contribution of hydration to aggregate fragmentation decreases, and the process of aggregate breakdown with different textures is characterized by size selectivity. When the soil aggregates were fragmented into 2–0.25 mm aggregate fractions, for silty loam and sandy clay loam, 0.002–0.02 mm and 0.002 mm particles were preferentially moved. When the soil aggregates were fragmented into <0.25 mm aggregate fractions for soils with different textures, the 0.002–0.02 mm and <0.002 mm particles all exhibited preferential migration characteristics. This work provides an idea for improving the methods of aggregate stability measurements in the future.