This paper reviews the progress in applying the plasma-driven solution electrolysis (PDSE), which is also referred to as the contact glow-discharge electrolysis (CGDE) or plasma electrolysis, for hydrogen production. The physicochemical processes responsible for the formation of PDSE and effects occurring at the discharge electrode in the cathodic and anodic regimes of the PDSE operation are described. The influence of the PDSE process parameters, especially the discharge polarity, magnitude of the applied voltage, type and concentration of the typical electrolytic solutions (K₂CO₃, Na₂CO₃, KOH, NaOH, H₂SO₄), presence of organic additives (CH₃OH, C₂H₅OH, CH₃COOH), temperature of the electrolytic solution, the active length and immersion depth of the discharge electrode into the electrolytic solution, on the energy efficiency (%), energy yield (g(H₂)/kWh), and hydrogen production rate (g(H₂)/h) is presented and discussed. This analysis showed that in the cathodic regime of PDSE, the hydrogen production rate is 33.3 times higher than that in the anodic regime of PDSE, whereas the Faradaic and energy efficiencies are 11 and 12.5 times greater, respectively, than that in the anodic one. It also revealed the energy yield of hydrogen production in the cathodic regime of PDSE in the methanol–water mixture, as the electrolytic solution is 3.9 times greater compared to that of the alkaline electrolysis, 4.1 times greater compared to the polymer electrolyte membrane electrolysis, 2.8 times greater compared to the solid oxide electrolysis, 1.75 times greater than that obtained in the microwave (2.45 GHz) plasma, and 5.8% greater compared to natural gas steam reforming.

This article presents the analysis of the electromagnetic (EM) properties of a novel metamaterial (MM) array in the microwave frequency range. The background for this work is the rapid development of portable devices with low individual energy consumption for the so-called “Internet of Things” (IoT) and the demand for energy harvesting from the environment on a micro scale through harvesters capable of powering billions of small receivers globally. The main goal of this work was to check the potential of the novel MM array structure for EM energy harvesting. The proposed MM array was analyzed in the CST Studio simulation environment. This resulted in the determination of the substitute average EM parameters (absorption, reflection, and transmission) of the MM array. Then, the MM array was manufactured, and the simulation results of the MM array parameters were experimentally validated in a microwave waveguide test system. Based on this conclusion, a prototype of the microwave MM absorber, together with an RF/DC converter, was designed and manufactured for harvesting EM energy from the environment. The system’s energy efficiency was evaluated, and its potential application in energy harvesting technology was appraised. Using a microwave horn antenna, the EM energy harvesting efficiency of the prototype was evaluated. It was about 50% at a microwave frequency of about 2.6 GHz. This may make the prototype attractive as an EM energy harvester or bolometric sensor.

Wireless data transmission in the hydroacoustic channel under non-line-of-sight (NLOS) propagation conditions, for example, during a wreck penetration, is difficult to implement reliably. This is mostly due to the multipath propagation, which causes a reduction in the quality of data reception. Therefore, in this work an attempt has been made to develop a reliable method of wireless underwater communication test it under the NLOS conditions. In our method, we used multiple frequency-shift keying (MFSK) modulation, sending a single bit on two carriers, and diversity combining. The method was tested in laboratory conditions which simulated underwater signal propagation during the penetration of the wreck. The propagation conditions were investigated by determining the impulse responses at selected measurement points using the correlation method. Additionally, for comparison, the data transmission quality was determined by the bit error rate (BER) under the same conditions using direct sequence spread spectrum (DSSS) and binary phase shift keying (BPSK) modulation. The obtained results confirmed the usefulness of the application of the developed method for wireless data transmission in a hydroacoustic channel under NLOS conditions.

The most likely intentional high-power electromagnetic (EM) interference, threatening the operation of technologically advanced electronic infrastructure, will have the forms of sub- and nanosecond ultra-wideband (UWB) pulses, several hundred nanosecond pulses of attenuated sinusoids, and sub- and microsecond sinusoidal pulses. The protection of electronic objects against high-power EM pulses is provided by different types of metal enclosure shields with technological apertures, inside which sensitive electronic objects can be placed. These technological apertures allow external EM interference to penetrate into the enclosure, making the EM shielding imperfect. The EM protection against the EM pulses has been mainly assessed based on the so-called shielding effectiveness (SE) parameters. The SE parameters (SE^e and SE^m for the electric and magnetic fields, respectively) are useful for designing and comparing EM shields. In relatively small shielding enclosures, which have recently become the subject of interest, the SE parameters have been studied for relatively long transient EM interference, longer than 150 ns, i.e., for the EM pulses whose duration is much longer than the time that the pulse takes to pass the small enclosure. In this work, we dealt with an ultrashort transient interference pulse, the duration of which was much shorter than the pulse transit time through the enclosure. The intentional high-power EM subnanosecond UWB pulse is an example of such a pulse. For such an ultrashort pulse, we studied the EM shielding performance of a small size enclosure numerically (W:H:D = 455 mm:50 mm:463 mm) with aperture (W:H = 80 mm:30 mm). The ultrashort EM interference pulse of a Gaussian distribution of the electric and magnetic fields with amplitudes of 10⁶ V/m and 2.68·10³ A/m, respectively, applied in this study, had a duration of 0.0804 ns (FWHM). This means that the high-power EM interference pulse was about 18 times shorter than the time that it takes to pass the enclosure (equal to about 1.5 ns). Our numerical simulations of the subnanosecond high-power EM interference of the interior of the enclosure with aperture were performed in the time domain using the commercial code CST Microwave Studio. First of all, the time-domain simulations resulted in 2D and 3D images and 2D vector maps of the electric and magnetic fields, which visualized the temporal and spatial development of the EM field in the enclosure with aperture caused by the incident subnanosecond high-power EM interference. The development of the associated electric and magnetic fields proceeded in two phases: first in the form of EM waves and later as an interference pattern, traveling forth and back between the front and rear enclosure walls. Due to the energy loss through the aperture, suffered by the traveling EM field and the tendency of the EM field to be evenly distributed over time throughout the entire enclosure, the amplitudes of the EM field decreased about 30 times within 90 ns. Despite the energy loss, the EM field developed in the enclosure existed at least 1000 times longer than the subnanosecond duration of the incident EM pulse (i.e., at least 90 ns as demonstrated by the numerical calculation). Apart from the EM field development visualization, the time-domain simulation enabled easy tracking of the temporal behavior of the EM field in selected points in the enclosure. Such tracking showed that each point in the enclosure was passed by a series of subnanosecond EM pulses, called internal EM pulses, over a relatively long time (at least over the simulation duration of 90 ns). This means that over 90 ns, the points in the enclosure were repeatedly influenced by the series of about 500 subnanosecond internal EM pulses. The amplitudes of many of these pulses were only (3–5) times lower than that of the incident EM pulse. Despite the lower amplitudes, these internal pulses may cause severe EM interference inside the enclosure. This shows a substantial change in the nature of the EM interference caused by a subnanosecond high-power EM plane wave when a given point is not shielded (a single interference of the subnanosecond strong EM pulse) and when a given point is shielded by the enclosure with aperture (a repetitive interference of subnanosecond weaker EM pulses). With the time dependence of the EM field amplitudes obtained from the time-domain calculation at a selected point in the enclosure, it is easy to determine the SE^e and SE^m at that point as a function of time. In this way, evaluation of the local SE^e and SE^m (for selected points in the enclosure) can be performed. Moreover, the 2D and 3D images and 2D vector maps calculated in the time domain for a given time enabled easy calculation of the SE^e and SE^m maps for various times. Such maps, shown for the first time in this paper, give a more global view of the shielding properties of the enclosure with an aperture. This all shows the advantages of the use of the time-domain approach for studying EM shielding in the case of ultrashort EM interferences.

Due to the increase in the threat of attacks with high-power electromagnetic (EM) pulses, there is great interest in metallic enclosures with high shielding effectiveness (SE). Necessary technological apertures in these enclosures reduce their effectiveness. Understanding the penetration and internal propagation of the high-power EM pulses into an apertured enclosure is fundamental to assessing the EM SE of the enclosure. In the present paper, results of the numerical simulations of development of the EM field in a shielding enclosure with aperture after the interference of a subnanosecond high-power EM plane wave pulse of the parallel polarization (having the duration of 0.3558 ns and the amplitudes of the electric and magnetic fields of 10⁶ V/m and 2.6 × 10³ A/m, respectively) are presented. The results obtained include 3D and 2D images , vector maps of the EM field developed inside the enclosure, and time-varying distributions of the electric charges formed on the inner walls of the enclosure. They revealed the mechanism of formation of the EM field inside the enclosure caused by the subnanosecond high-power parallelly polarized EM pulse. The EM field formed in the enclosure with aperture has the form of the electric and magnetic field interference structures. They are a superposition of the incident EM pulse field, which entered the enclosure through the aperture in the way described by the geometrical (ray) optics, the electric field generated by the electric charges formed on the aperture edges and inner sides of the walls of the enclosure, and the magnetic field generated by the surface current formed on the aperture edges and on the inner walls of the enclosure. The amplitudes of the electric and magnetic fields of the strongest EM interference structures decrease non-monotonically to about 0.7 × 10⁵ V/m and 200 A/m at t = 5 ns. We found that the points in the enclosure are subjected to the disturbance of a long series of subnanosecond EM pulses, which we have called internal EM pulses. The amplitudes of these internal pulses are lower than those of the incident EM pulse. Nevertheless, they can pose a severe EM hazard inside the enclosure due to their large number (about 900 internal pulses in 30 ns). This means a fundamental change in the character of the EM disturbance caused by the subnanosecond pulse when the enclosure with aperture is used as a shield.