High quality silver (Ag) decorated CeO₂ nanoparticles were prepared by a facile one-step chemical method. The samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), High resolution transmission electron microscopy (HR-TEM), fourier transform infrared spectrometer (FT-IR), electron paramagnetic resonance (EPR), X-ray photoelectron spectroscopy (XPS), UV–Visible absorption (UV–Vis), photoluminescence (PL) and thermogravimetric analysis. The decoration of Ag on CeO₂ surface was confirmed by XRD, EPR and HR-TEM analysis. Harmful textile pollutant Rose Bengal dye was degraded under sunlight using the novel Ag decorated CeO₂ catalyst. It was found that great enhancement of the degradation efficiency for Ag/CeO₂ compared to pure CeO₂, it can be ascribed mainly due to decrease in its band gap and charge carrier recombination rate. The Ag/CeO₂ sample exhibited an efficient photocatalytic characteristic for degrading RB under visible light irradiation with a high degradation rate of 96% after 3 h. With the help of various characterizations, a possible degradation mechanism has been proposed which shows the effect of generation of oxygen vacancies owing to the decoration of Ag on the CeO₂ surface.

A facile one-step chemical method is introduced for the successful synthesis of Cu₂O, CuO and CuNa₂(OH)₄crystal structures and their electrochemical properties were also investigated. X-ray diffraction studies revealed that these copper-based oxide nanoparticles display different crystal structures such as cubic (Cu₂O), monoclinic (CuO) and orthorhombic [CuNa₂(OH)₄]. The microstructural information of nanoparticles was investigated by transmission electron microscopy. It shows attractive morphologies of different orientation such as rod like structure, nanobeads and well-aligned uniform nanorod for Cu₂O, CuO and CuNa₂(OH)₄, respectively. Electrochemical sensing of sulphite (SO₃²⁻) on these three copper-based oxide modified electrodes was investigated. Among the three different crystal structures, CuO shows promising electrocatalytic activity towards oxidation of sulphite. A linear variation in peak current was obtained for SO₃²⁻oxidation from 0.2 to 15 mM under the optimum experimental condition. The sensitivity and detection limit were in the order of 48.5 µA cm⁻² mM⁻¹and 1.8 µM, respectively. Finally, practical utility of CuO modified electrode was demonstrated for the estimation of sulphite in commercial wine samples.

MXenes, a novel family of 2D transition metal carbide, nitride and carbonitride materials, have been gaining tremendous interest in recent days as potential electrocatalysts for various electrochemical reactions, including hydrogen evolution reaction (HER). MXenes are characterized by their etchable metal layers, excellent structural stability, versatility for heteroatoms doping, excellent electronic conductivity, unique surface functional groups and admirable surface area, suitable for the role of electrocatalyst/support in electrochemical reactions, such as HER. In this review article, we summarized recent developments in MXene-based electrocatalysts synthesis and HER performance in terms of the theoretical and experimental point of view. We systematically evaluated the superiority of the MXene-based catalysts over traditional Pt/C catalysts in terms of HER kinetics, Tafel slope, overpotential and stability, both in acidic and alkaline electrolytic environments. We also pointed out the motives behind the electro catalytic enhancements, the effect of synthesis conditions, heteroatom doping, the effect of surface terminations on the electrocatalytic active sites of various MXenes families. At the end, various possible approaches were recommended for a deeper understanding of the active sites and catalytic improvement of MXenes catalysts for HER.

Today’s world requires high-performance energy storage devices such as hybrid supercapacitors (HSc), which play an important role in the modern electronic market because supercapacitors (Sc) show better electrical properties for electronics devices. In the last few years, the scientific community has focused on the coupling of Sc and battery-type materials to improve energy and power density. Recently, various hybrid electrode materials have been reported in the literature; out of these, coordination polymers such as metal-organic frameworks (MOFs) are highly porous, stable, and widely explored for various applications. The poor conductivity of classical MOFs restricts their applications. The composite of MOFs with highly porous graphene (G), graphene oxide (GO), or reduced graphene oxide (rGO) nanomaterials is a promising strategy in the field of electrochemical applications. In this review, we have discussed the strategy, device structure, and function of the MOFs/G, MOFs/GO, and MOFs/rGO nanocomposites on Sc. The structural, morphological, and electrochemical performance of coordination polymers composites towards Sc application has been discussed. The reported results indicate the considerable improvement in the structural, surface morphological, and electrochemical performance of the Sc due to their positive synergistic effect. Finally, we focused on the recent development in preparation methods optimization, and the opportunities for MOFs/G based nanomaterials as electrode materials for energy storage applications have been discussed in detail.