Ionic liquids have attracted the attention of the industry and research community as versatile solvents with unique properties, such as ionic conductivity, low volatility, high solubility of gases and vapors, thermal stability, and the possibility to combine anions and cations to yield an almost endless list of different structures. These features open perspectives for numerous applications, such as the reaction medium for chemical synthesis, electrolytes for batteries, solvent for gas sorption processes, and also membranes for gas separation. In the search for better-performing membrane materials and membranes for gas and vapor separation, ionic liquids have been investigated extensively in the last decade and a half. This review gives a complete overview of the main developments in the field of ionic liquid membranes since their first introduction. It covers all different materials, membrane types, their preparation, pure and mixed gas transport properties, and examples of potential gas separation applications. Special systems will also be discussed, including facilitated transport membranes and mixed matrix membranes. The main strengths and weaknesses of the different membrane types will be discussed, subdividing them into supported ionic liquid membranes (SILMs), poly(ionic liquids) or polymerized ionic liquids (PILs), polymer/ionic liquid blends (physically or chemically cross-linked ‘ion-gels’), and PIL/IL blends. Since membrane processes are advancing as an energy-efficient alternative to traditional separation processes, having shown promising results for complex new separation challenges like carbon capture as well, they may be the key to developing a more sustainable future society. In this light, this review presents the state-of-the-art of ionic liquid membranes, to analyze their potential in the gas separation processes of the future.

Organic dyes such as methyl orange (MO) and methylene blue (MB) are widely used in different industries and have become one of the leading emerging water contaminants. The purpose of the current research is to develop new polymer nanocomposite filters for the effective elimination of the dyes, which are non-biodegradable and not efficiently removed by traditional treatment methods. New padded and covered filters were produced applying polystyrene-acrylic/ZnO nanocomposite on the polyester surface by blade coating and one-bath pad methods. Principal results determined by SEM analysis confirm that functionalised layer can create unprecedented function of filter textile material depending on the way of treatment. Due to the modification, the surface area increased from 5.9 for untreated polyester to 85.2 (padded), 44.6 (covered) m²/g. The measured pore size of produced filters is around 3.4 nm, which corresponds to the mesoporous structure. Our study reported effective filters with the rate of MB and MO removal efficiencies up to 60%. Moreover, a colourless reduced form of MB—leuco-methylene blue (LMB) could be created. The functionalised layer of the developed filters through hydrogen bonding between the –OH groups of styrene-acrylic molecules and the –N(CH₃)₂ groups on LMB can stabilise LMB.

Ibuprofen separation from water by adsorption and pertraction processes has been studied, comparing 16 different membranes. Tailor-made membranes based on Matrimid, Ultem, and diaminobenzene/diaminobenzoic acid with various contents of zeolite and graphene oxide, have been compared to the commercial polystyrene, polypropylene, and polydimethylsiloxane polymeric membranes. Experimental results revealed lower ibuprofen adsorption onto commercial membranes than onto tailor-made membranes (10–15% compared to 50–70%). However, the mechanical stability of commercial membranes allowed the pertraction process application, which displayed a superior quantity of ibuprofen eliminated. Additionally, the saturation of the best-performing commercial membrane, polydimethylsiloxane, was notably prevented by atomic layer deposition of (3-aminopropyl)triethoxysilane.

Pharmaceutical wastewater pollution has reached an alarming stage, as many studies have reported. Membrane separation has shown great performance in wastewater treatment, but there are some drawbacks and undesired byproducts of this process. Selective membranes could be used for pollutant investigation sensors or even for pollutant recovery. The polydimethylsiloxane (PDMS) membrane was first tested on separated and mixed antibiotic (ATB) water solutions containing sulfamethoxazole (SM), trimethoprim (TMP), and tetracycline (TET). Then, the bare and ultra-violet grafted (UV-grafted) PDMS membranes (MMA-DMAEMA 10, GMA-DMAEMA 5, and GMA-DMAEMA 10) were tested in tramadol (TRA) separation, where the diffusion coefficient was evaluated. Finally, the membranes were tested in pertraction with a mixture of SM, TMP, TET, and TRA. The membranes were characterized using the following methods: contact angle measurement, FTIR, SEM/EDX, and surface and pore analysis. The main findings were that TET was co-eluted during mixed ATB pertraction, and GMA-DMAEMA 5 was found to selectively permeate TRA over the present ATBs.

Використання технологій едьютейнмент в методиці навчання хімії в школі

Organic dyes such as Methyl Orange (MO) and Methylene Blue (MB) are widely used in different industries, becoming one of the leading emerging water contaminants. It is urgent to develop the most suitable materials for effective elimination of the dyes as they are non-biodegradable and are not removed efficiently by the traditional treatment methods. The present work applied polystyrene-acrylic/ZnO nanocomposite on the polyester surface by blade coating and one-bath pad methods. Features of surface chemical modifications were determined by FTIR, SEM analysis, WCA, N₂ adsorption-desorption isotherms. The functionalised layer can create unprecedented function of filter textile material depending on the way of treatment. The possibility of using such fabrics as filters was explored for MO and MB in the concentration of 100 ppm. Water purification occurred by 60% from methylene blue and 40% from methylene orange flowing through the padded polyester filter and the covered polyester filter for 2 min, respectively. Moreover, it was shown that a colourless reduced form of MB – leuco-methylene blue (LMB) could be created. The functionalised layer of the developed filters through hydrogen bonding between the –OH groups of styrene-acrylic molecules and the –N(CH₃)₂ groups on LMB can stabilise LMB.