The aim of the study was to determine whether using chemical and radiochemical analysis of lake sediments can highlight changes in the climate. Also it was studied whether human impact on the environment can be observed and to what extent such changes are in agreement with historical data. Samples of 16 cm thick sediment cores from the Smreczynski Staw Lake were collected and divided into 1 cm thick sub-samples. The samples were air dried and homogenized. The quantitative analysis of Fe, Mn, Zn, Cr, Cu, Ni, Cd, and Pb in the digested sediment samples was made by using atomic absorption spectrometry. Simultaneously, the radioactivity of 137Cs using gamma spectrometry and 210Pbuns using alpha spectrometry, were measured for sediment layer dating. Results showed that iron concentration was in the range 0.3–over 1 % (w/w), and zinc 0.01–0.05 % (w/w). Lesser concentrations were found for copper 18.37–43.6 ppm, manganese 37.5–50.7 ppm, lead 146.1–432 ppm, chromium 12.3–37.4 ppm, nickel 3.1–10.8 ppm and cadmium 0.9–34.6 ppm. Changes in 137Cs radioactivity was in the range of 89 ± 11 to 865 ± 62 (Bq kg−1). Sediments composition can accurately reflect (in terms of time and to what extent) air pollution and natural geo-chemical processes in the environment. However, the choice of the analysed object is crucial in this respect. The Smreczynski Staw Lake, due to its location in the mountains and hydrological situation, proved to be very useful for providing undisturbed analytical samples.
16 January 2019 in Environmental Science and Pollution Research
The analyzed sediments were taken from the man-made reservoirs (Velka Richnava, Rozgrund and Vindsachta) located in an area intensively mined for polymetallic ores since the end of the eleventh century (Banska Stiavnica region, Central Europe). The aims of this study were to determine the radioactivity of natural (226Ra, 228Th, 210Pb) and artificial (137Cs and 241Am) radionuclides, compare the radionuclides’ distribution, and indicate the correlation of radioisotopes and their origin related to sediment properties. Two analytical techniques were used. 228Th, 226Ra, 241Am, and 137Cs were measured by means of gamma spectrometry and 210Pb was determined by its daughter radionuclide 210Po using alpha spectrometry. The results showed that the highest mean level of 226Ra (42.6 Bq·kg−1), 228Th (49.7 Bq·kg−1) and 210Pb (75.2 Bq·kg−1) was in the sediments collected from Rozgrund. The radioactivity of 137Cs and 241Am were present at a higher level in the layer related to Chernobyl (1986) accident and nuclear weapon test (1950/1960). The distribution of natural radionuclides was quite similar in all reservoirs. Chemometric analysis confirmed the radionuclides’ origin and correlation between the analyzed parameters.
17 November 2017 in Environmental Science and Pollution Research
The Sudety Mts. form a chain of mountains in the South of Poland and during the last 200 years were subjected to strong industrial and agricultural pressure. The records of these human-induced changes are stored in natural archives like lake sediments. For the comprehensive study, three sediment cores taken from Mały Staw Lake (Sudety Mts.) were analyzed for the concentration of K, Na, Mn, Fe, Cu, Mg, Zn, Cd, Cr, Ni, Pb and radioactivity of 137Cs and 210Pb. As a result of the studies, the bathymetry map was developed and the sources of solid material supplied to the lake were identified. The geochronology studies of the cores were performed using 210Pb method, to evaluate model of time changes in the sediment. Radioactivity of 210Pbuns (determined indirectly by 210Po) ranged from 1051 ± 64 to 12 ± 8 Bq kg−1. The 137Cs radioactivity was determined directly by gamma spectrometry and varied from 525 ± 37 Bq kg−1 for top layers to 9.80 ± 5.40 Bq kg−1 for the bottom of the core. Two characteristic peaks of 137Cs radioactivity related to the global fallouts after nuclear weapons testing and the Chernobyl accident were observed and used to confirm 210Pb dating method. Chemometrics analysis of the chosen metal’s concentrations combined with sample dating showed distinct imprint of human activity on the studied area.
The work aimed to show the applicability of geological studies to the investigation of radiation risk assessment due to the presence of naturally occurring radionuclides of terrestrial origin in the soil. Soil samples were taken from a Tatra Mountains area for which geological maps were available. The concentration of selected radionuclides incl. 40K, 238U and 232Th was determined by gamma-ray spectrometry with a HPGe-detector. Radioactivities and calculated absorbed dose rates were co-related to complex bedrock matrices based on an original methodology. The correlations were proved by performing a Principal Component Analysis (PCA). The rocks that had a significant impact on the rate of absorbed dose from the soil were strongly related to the radioactivity of the uranium series. The share of the following fractions was the most significant: granite with pegmatite, gneiss, granitoid and gneiss, coquina, marl and glauconite, hard limestone, dolomite and limestone. The rock types additionally showed good correlation with radioisotopes from the thorium series. Granitoids with potassium feldspar, on the other hand, contributed the largest share of 40K radioisotope content.
1 September 2018 in Palaeogeography, Palaeoclimatology, Palaeoecology