Stable topological defects of light (pseudo)scalar fields can contribute to the Universe’s dark energy and dark matter. Currently, the combination of gravitational and cosmological constraints provides the best limits on such a possibility. We take an example of domain walls generated by an axionlike field with a coupling to the spins of standard-model particles and show that, if the galactic environment contains a network of such walls, terrestrial experiments aimed at the detection of wall-crossing events are realistic. In particular, a geographically separated but time-synchronized network of sensitive atomic magnetometers can detect a wall crossing and probe a range of model parameters currently unconstrained by astrophysical observations and gravitational experiments.

We review experimental techniques in our laboratory for nuclear magnetic resonance (NMR) in zero and ultralow magnetic field (below 0.1 $\mu$ T) where detection is based on a low-cost, non-cryogenic, spin-exchange relaxation free ⁸⁷Rb atomic magnetometer. The typical sensitivity is 20-30 fT/Hz^1/2 for signal frequencies below 1 kHz and NMR linewidths range from Hz all the way down to tens of mHz. These features enable precision measurements of chemically informative nuclear spin-spin couplings as well as nuclear spin precession in ultralow magnetic fields.

Recent work investigating resonant nonlinear magneto-optical rotation (NMOR) related to long-lived $({\tau }_{\mathrm{rel}}\sim 1\mathrm{s})$ ground-state atomic coherences has demonstrated potential magnetometric sensitivities exceeding ${10}^{-11}\mathrm{G}∕\sqrt{\mathrm{Hz}}$ for small $(\lesssim 1\mathrm{\mu }\mathrm{G}$) magnetic fields. In the present work, NMOR using frequency-modulated light (FM NMOR) is studied in the regime where the longitudinal magnetic field is in the geophysical range$(\sim 500\mathrm{mG})$, of particular interest for many applications. In this regime a splitting of the FM NMOR resonance due to the nonlinear Zeeman effect is observed. At sufficiently high light intensities, there is also a splitting of the FM NMOR resonances due to ac Stark shifts induced by the optical field, as well as evidence of alignment-to-orientation conversion type processes. The consequences of these effects for FM-NMOR-based atomic magnetometry in the geophysical field range are considered.

Using laser optical pumping, widths and frequency shifts are determined for microwave transitions between ground-state hyperfine components of ${}^{85}\mathrm{Rb}$ and ${}^{87}\mathrm{Rb}$ atoms contained in vapor cells with alkane antirelaxation coatings. The results are compared with data on Zeeman relaxation obtained in nonlinear magneto-optical rotation experiments, a comparison important for quantitative understanding of spin-relaxation mechanisms in coated cells. By comparing cells manufactured over a $40\text{‐}\text{year}$ period we demonstrate the long-term stability of coated cells, an important property for atomic clocks and magnetometers.

The technique of nonlinear magneto-optical rotation with amplitude modulated light is developed. The technique is an alternative to its counterpart with frequency modulated light and can be applied to sensitive measurements of magnetic fields ranging from microgauss to the Earth-field level. The rotation signals exhibit nontrivial features such as narrowed non-Lorentzian line shapes and multicomponent resonances.