Significant drying shrinkage is one of the main limitations for the wider utilization of alkali-activated slag (AAS). Few previous works revealed that it is possible to reduce AAS drying shrinkage by the use of shrinkage-reducing admixtures (SRAs). However, these studies were mainly focused on SRA based on polypropylene glycol, while as it is shown in this paper, the behavior of SRA based on 2-methyl-2,4-pentanediol can be significantly different. While 0.25% and 0.50% had only a minor effect on the AAS properties, 1.0% of this SRA reduced the drying shrinkage of waterglass-activated slag mortar by more than 80%, but it greatly reduced early strengths simultaneously. This feature was further studied by isothermal calorimetry, mercury intrusion porosimetry (MIP) and scanning electron microscopy (SEM). Calorimetric experiments showed that 1% of SRA modified the second peak of the pre-induction period and delayed the maximum of the main hydration peak by several days, which corresponds well with observed strength development as well as with the MIP and SEM results. These observations proved the certain incompatibility of SRA with the studied AAS system, because the drying shrinkage reduction was induced by the strong retardation of hydration, resulting in a coarsening of the pore structure rather than the proper function of the SRA.
In recent years, the utilization of different non-traditional cements and composites has been increasing. Alkali-activated cementitious materials, especially those based on the alkali activation of blast furnace slag, have considerable potential for utilization in the building industry. However, alkali-slag cements exhibit very rapid setting times, which are too short in some circumstances, and these materials cannot be used for some applications. Therefore, it is necessary to find a suitable retarding admixture. It was shown that the sodium phosphate additive has a strong effect on the heat evolution during alkali activation and effectively retards the hydration reaction of alkali-activated blast furnace slag. The aim of the work is the suggestion of a reaction mechanism of retardation mainly based on Raman and X‑ray photoelectron spectroscopy.
Fiber-reinforced concrete has a wide application in practice, and many fields of research are devoted to it. In most cases, this is a specific problem, i.e., the determination of the mechanical properties or the test method. However, wider knowledge of the effect of fiber in concrete is unavailable or insufficient for selected test series that cannot be compared. This article deals with the processing of a comprehensive test study and the impact of two types of fibers on the quantitative and qualitative parameters of concrete. Testing was performed for fiber dosages of 0, 40, 75, and 110 kg/m3. The fibers were hooked and straight. The influence of the fibers on the mechanical properties in fiber-reinforced concrete was analyzed by functional dependence. The selected mechanical properties were compressive strength, splitting tensile strength, bending tensile strength, and fracture energy. The results also include the resulting load–displacement diagrams and summary recommendations for the structural use and design of fiber-reinforced concrete structures. The shear resistance of reinforced concrete beams with hooked fibers was also verified by tests.
1 March 2018 in Construction and Building Materials