In the context of a circular economy, special attention should be paid to the rational management of biodegradable waste. Currently, a potentially valuable waste material, rich in ingredients available to plants, is digestate, obtained as a by-product in agricultural biogas plants. The presented study aimed to determine the impact of digestate (DIG) from an agricultural biogas plant on soil reaction (pH), electrical conductivity (EC), sorption properties (SBC, HAC, CEC, BS), and chemical composition of soil. The research was based on a pot experiment in which increasing doses of liquid (LD) and solid (SD) forms of DIG were used in corn cultivation, balanced in terms of the amount of N introduced into the soil. The composition of DIG varied and depended on the LD or SD form. The LD was characterized by a lower pH value and higher EC compared to the SD form. The LD contained much less TC, fewer macroelements, and fewer trace elements. The application of LD significantly increased in the soil the content of TC, N_tot, available K, P, Fe, and Mn, and exchangeable cations K⁺. The SD significantly increased the content of available P, Mg, and Mn and exchangeable cations Ca²⁺ and Mg²⁺ in the soil. Both forms of digestate increased the total content of heavy metals (Cu, Cr, Pb, and Ni) in the soil. However, they did not pose a threat to the environment concerning their legally permissible levels.

The aim of the investigation was to evaluate the response of plants, using black mustard (Brassica nigra L. Koch) as a model plant, to soil contamination with copper (0, 200, 400, 600 mg Cu kg⁻¹ of soil), and to determine the effectiveness of the Cu immobilization with mineral neutralizing materials, such as lime, clay and zeolite. The plant yield depended on soil contamination and mineral amendments. In the series without neutralizing materials, the level of 600 mg Cu kg⁻¹ reduced the yield and increased leaf greenness. Lime alleviated the toxicity of Cu in objects with 200 mg Cu kg⁻¹. Zeolite slightly mitigated the harmful effects of Cu at the level of 400 and 600 mg kg⁻¹. Zeolite lowered the SPAD index. In the chemical composition of plants, the content of Cu, K, Mg, Na and Ca in plants increased to 400 mg Cu kg⁻¹, while the content of P decreased to 600 mg Cu kg⁻¹. Among the materials, lime reduced the Cu accumulation in plants the most, followed by clay. Cu narrowed the majority of ratios and widened the Ca:P and K:Ca ratios in plants. The applied mineral materials, except lime, did not significantly affect the formation of these indicators.

The paper discusses the problem of the impact of the road on the content of heavy metals in soil and the impact of land use on limiting the migration of these xenobiotics. The area submitted to the research stretched along Sielska Street in Olsztyn, which is a section of the DK 16 route connecting Olsztyn and Ostróda. This area varies in terms of land relief, land use and plant cover. Soil samples were taken on both sides of the street at a distance of 1, 10 and 20 m from the road. The content of trace elements (Cd, Cr, Ni, Co, Cu, Pb, Zn, Mn and Fe), soil reaction (pH), salinity (EC) and total organic carbon (TOC) were determined in the soil. The enrichment factor (EF) was calculated. The content of heavy metals in soil was relatively low and did not exceed the relevant standard values [1]. Significantly higher content of Cd, Cu, Zn and Mn and the EC value were noted on the northern side of the street, which to some extent could be attributed to the position of this area along an outward bend of the road. Values of EF obtained for: Cd, Pb, Zn, Cu, Co, and Ni may indicate their anthropogenic accumulation in soil. Moreover, the study showed that appropriate management of the land (a green belt, a hedge, trees) can reduce the translocation of heavy metals over larger distances.

Poultry farming involves the production of poultry manures (PMs), which, if properly managed, are excellent organic soil amendments. Poultry farms generally do not have adequate arable land, and therefore, valuable fertilizer becomes a problematic waste. During the production and storage of PMs, odorous VOCs, NH₄, H₂S, and potent greenhouse gases such as CH₄, CO₂ are emitted. It influences the productivity of poultry and negatively affects the working conditions of working staff. In the present study, mineral–microbial deodorizing preparations (MMDP) based on perlite and bentonite as well as the following microorganism strains Lactobacillus plantarum, Leuconostoc mesenteroides, Bacillus megaterium, B. subtilis, and Pseudomonas fluorescens were added to the litter of turkey broilers (TB) and egg-laying hens (LH). PMs were compared with treatments without the addition of MMDP, and maize, sunflower, and rapeseed forage crops were tested. The influence on soil parameters such as pH, EC, HAC, SBC, CEC, BS, N_tot, C_tot, and plant yield and parameter of photosynthesis, i.e., SPAD index, was tested. Soil amending with manure resulted in an increase in pH and a decrease in HAC; in addition, an increase in EC, which was counteracted by the addition of MMDP, was noted. MMDP positively affected parameters such as SBC, CEC, and BS. It was shown that PMs, with the addition of MMDP, improved crops’ yield in the first year of the study, whereas this effect was not seen for the after-crop plants (lupine). The main ‘added value’ related to the usage of MMDP in poultry production is the improvement in the properties of PMs, which mainly had a positive effect on soil indicators.

The research was based on a pot experiment in which the impact of increasing Cd, Zn and Pb doses on the content of available trace elements in soil was compared. Seven series of trials were designed: 1 (Cd), 2 (Pb), 3 (Zn), 4 (Cd + Pb), 5 (Cd + Zn), 6 (Pb + Zn), 7 (Cd + Pb + Zn). Aside from the control one (without the metals), three increasing levels of contamination were considered within each series. Mobile forms of trace elements (Cd, Pb, Zn, Fe, Mn, Cu, Ni, Co, and Cr) in soil were determined, in addition to which selected physicochemical soil properties—reaction (pH), salinity (EC), hydrolytic acidity (HAC), total exchange bases (TEB)—were identified while cation exchange capacity (CEC), base saturation (BS) and availability factor (AF) were calculated. The application of Cd and Pb to soil resulted in an increase in the share of potentially available forms of these metals in their total content. The availability factor (AF) in the pots polluted with these metals was higher than in the control, in the range 17.5–20.0% for Cd, and 62.8–71.5% for Pb. In turn, the share of Zn mobile forms was comparable in most experimental objects, oscillating around 30%. Moreover, addition to soil of Cd, Pb and Zn usually caused a significant decrease in the content of available forms of Fe, Mn and Cu, and resulted in significantly higher content of available forms of Cr in the soil.

Nowadays, we have observed the dynamic development of bio-heating plants that use wood biomass for heating or energy purposes. The result of this process is a reduction in carbon dioxide emissions as well as in the production of biomass ash (BA). Despite the waste nature of BA, it should be carefully analyzed and assessed for various applications, including environmental ones. Due to the features attributed to BA, including its alkaline reaction, the high capacity of its sorption complex, relatively low salinity, and significant content of macro- and microelements, a hypothesis was put forward in this work undertaken about the positive role of BA as an immobilizing factor for Cd-, Pb-, and Zn-contaminated soils. This research was based on a pot experiment in which four series were considered: (1) BA; (2) BA + Cd; (3) BA + Pb; and (4) BA + Zn. BA was used at doses of 30, 60, and 90 mg pot⁻¹, and metals at doses of 2 mg Cd, 100 mg Pb, and 300 mg Zn kg⁻¹ of soil. The test plant was corn grown for green mass. The study took into account the influence of BA on the content of the total forms of heavy metals (Me_tot) and their available forms (Me_av). In the soil without the addition of metals, a significant increase in the content of Cd_tot and Cd_av, and a decrease in the content of Zn_tot were observed due to the application of BA. The addition of metals against the background of the BA used resulted in a significant increase in Cd_tot, Pb_tot, and Zn_tot, as well as an increase in the available forms of Pb_av but a decrease in Zn_av. However, there was no significant increase in the Cd_av content. The obtained results may indicate the potentially immobilizing role of BA only in the case of zinc. They may constitute the basis for further, more detailed research aimed at determining the role of BA in the immobilization of various metals in soil.