Produced water (PW), the largest waste stream generated in oil and gas industries, has the potential to be a harmless product rather than being a waste. Biological processes using microorganisms have proven useful to remediate PW contaminated by petroleum hydrocarbons, complex organic chemicals, and solvents. In particular, the bioremediation of PW using algae is an eco-friendly and low-cost approach due to algae’s ability to utilize certain pollutants as nutrient sources. Therefore, the utilization of PW as an algal growth medium has a great potential to eliminate chemicals from the PW and minimize the large volumes of freshwater needed for cultivation. Although several reviews describing the bioremediation of PW have been published, to the best of our knowledge, no review has exclusively focused on the algae-based PW treatment. Therefore, the present review is dedicated to filling this gap by portraying the many different facets of the algae cultivation in PW. Several algal species that are known to thrive in a wide range of salinity and the critical steps for their cultivation in hypersaline PW have been identified. Overall, this comprehensive review highlights the PW bioremediation using algae and brings attention to utilizing PW to grow biomass that can be processed to generate biofuels and useful bioproducts.
Solid waste generation has been projected to increase worldwide. Presently, the most applied methodology to dispose of solid waste is landfilling. However, these landfill sites, over time release a significant quantity of leachate, which can pose serious environmental issues, including contamination of water resources. There exist many physicochemical and biological landfill leachate treatment schemes with varying degrees of success. With an increasing focus on sustainability, there has been a demand for developing eco-friendly, green treatment schemes for landfill leachates with viable resource recovery and minimum environmental footprints. Microalgae-based techniques can be a potential candidate for such a treatment scenario. In this article, research on microalgae-based landfill leachate treatments reported in the last 15 years have been summarized and critically reviewed. The scale-up aspect of microalgae technology has been discussed, and the related critical factors have been elucidated. The article also analyzes the resource recovery potential for microalgal techniques with respect to leachate treatment and explores possible methodologies to minimize the environmental footprints of the microalgae-based treatment process. The future research potential in the area has been identified and discussed.
In the past few decades, the role of nanotechnology has expanded into environmental remediation applications. In this regard, nanofibers have been reported for various applications in water treatment and air filtration. Nanofibers are fibers of polymeric origin with diameters in the nanometer to submicron range. Electrospinning has been the most widely used method to synthesize nanofibers with tunable properties such as high specific surface area, uniform pore size, and controlled hydrophobicity. These properties of nanofibers make them highly sought after as adsorbents, photocatalysts, electrode materials, and membranes. In this review article, a basic description of the electrospinning process is presented. Subsequently, the role of different operating parameters in the electrospinning process and precursor polymeric solution is reviewed with respect to their influence on nanofiber properties. Three key areas of nanofiber application for water treatment (desalination, heavy-metal removal, and contaminant of emerging concern (CEC) remediation) are explored. The latest research in these areas is critically reviewed. Nanofibers have shown promising results in the case of membrane distillation, reverse osmosis, and forward osmosis applications. For heavy-metal removal, nanofibers have been able to remove trace heavy metals due to the convenient incorporation of specific functional groups that show a high affinity for the target heavy metals. In the case of CECs, nanofibers have been utilized not only as adsorbents but also as materials to localize and immobilize the trace contaminants, making further degradation by photocatalytic and electrochemical processes more efficient. The key issues with nanofiber application in water treatment include the lack of studies that explore the role of the background water matrix in impacting the contaminant removal performance, regeneration, and recyclability of nanofibers. Furthermore, the end-of-life disposal of nanofibers needs to be explored. The availability of more such studies will facilitate the adoption of nanofibers for water treatment applications.
This study aims to evaluate the potential of using a thermophilic acidophilic red alga, Galdieria sulphuraria for effective on-site treatment of municipal landfill leachate (LL). This study focused on evaluating the effects of LL dilution, nitrogen loading, and initial algal biomass density on the overall treatment efficiency, and evaluated the long-term performance of the system using 5-day growth cycles. This study confirmed that optimal conditions for G. sulphuraria biomass production are 20% strength LL, a lower initial biomass concentration of 0.25 g L−1, and the addition of N at twice the level of initial media. Furthermore, the results indicated G. sulphuraria’s ability to grow in elevated NH4-N concentration (>950 mg L−1) and provide nitrogen removal rates of up to 40 mg L−1 d−1. In addition, the long-term running experiment showed that the proposed algal-based system could be applied in semi-continuous mode to achieve bioremediation. Overall, the results obtained from this study can be used to develop the necessary process parameters to implement large-scale algal-based systems for landfill leachate treatment.