Conventionally, unfilled wax has been used as a universal pattern material for the investment casting process. With increase in demand for accurate dimensions and complex shapes, various materials have been blended with wax to develop more suitable patterns for investment casting in order to overcome performance limitations exhibited by unfilled wax. The present article initially reviews various investigations on the development of investment casting patterns by exploring pattern materials, type of waxes and their limitations, the effect of filler materials and various additives on unfilled wax, wax blends for pattern materials, plastics and polymers for pattern materials and 3D-printed patterns. The superiority of filled and polymer patterns in terms of dimensional accuracy, pattern strength, surface and flow properties over unfilled wax is also discussed. The present use of 3D patterns following their versatility in the manufacturing sector to revolutionize the investment casting process is also emphasized. Various studies on wax characterization such as physical (surface and dimensions), thermal (thermogravimetric analysis and differential scanning calorimetry), mechanical (thermomechanical analysis, tensile stress testing, dynamic mechanical analysis) and rheological (viscosity and shearing properties) are also discussed.

The disposal of industrial brine sludge waste (IBSW) in chlor-alkali plants can be avoided by utilization of IBSW as a sorbent in wet flue gas desulfurization (FGD). The shrinking core model was used to determine the dissolution kinetics of IBSW, which is a vital step in wet FGD. The effects of solid-to-liquid ratio (m/v), temperature, pH, particle size, and stirring speed on the conversion and dissolution rate constant are determined. The conversion and dissolution rate constant decreases as the pH, particle size, and solid-to-liquid ratio are increased and increases as the temperature, concentration of acid, and stirring speed are increased. The sorbents before and after dissolution were characterized using x-ray fluorescence (XRF), x-ray diffraction (XRD), and scanning electron microscopy (SEM). An activation energy of 7.195 kJ/mol was obtained and the product layer diffusion model was found to be the rate-controlling step. Implications: The use of industrial brine sludge waste as an alternative sorbent in wet flue gas desulfurization can reduce the amounts of industrial wastes disposed of in landfills. This study has proved that the sorbent can contain up to 91% calcium carbonate and trace amounts of sulfate, magnesium, and so on. This can be used as new sorbent to reduce the amount of sulfur dioxide in the atmosphere and the by-product gypsum can be used in construction, as a plaster ingredient, as a fertilizer, and for soil conditioning. Therefore, the sorbent has both economic and environmental benefits.