MOF–derived porous carbon is a type of promising catalyst to replace expensive Pt–based catalysts for oxygen reduction reaction (ORR). The catalytic activity for ORR depends closely on pyrolysis conditions. In this work, a Co–doped ZIF–8 material was chosen as a research object. The effect of pyrolysis conditions (temperature, heating rate, two–step heating) on the ORR performance of ZIF–derived carbon catalysts was systematically studied. The Co–ZIF–8 catalyst carbonized at 900 °C exhibits better ORR catalytic activity than that carbonized at 800 °C and 1000 °C. Moreover, a low heating rate can enhance catalytic activity. Two–step pyrolysis is proven to be an effective way to improve the performance of catalysts. Reducing the heating rate in the low–temperature stage is more beneficial to the ORR performance, compared to the heating rate in the high–temperature stage. The results show that the Co–ZIF–8 catalyst exhibits the best performance when the precursor was heated to 350 °C at 2 °C/min, and then heated to 900 °C at 5 °C/min. The optimum Co–ZIF–8 catalyst shows a half–wave potential of 0.82 V and a current density of 5.2 mA·cm−2 in 0.1 M KOH solution. It also exhibits high content of defects and good graphitization. TEM mapping shows that Co and N atoms are highly dispersed in the polyhedral carbon skeleton. However, two–step pyrolysis has no significant effect on the stability of the catalyst.
A magnetic levitation isolation system applied for the active control of micro-vibration in space requires actuators with high accuracy, linear thrust and low power consumption. The magneto-force-thermal characteristics of traditional electromagnetic actuators are not optimal, while actuators with a Halbach array can converge magnetic induction lines and enhance the unilateral magnetic field. To improve the control effect, an accurate magnetic field analytical model is required. In this paper, a magnetic field analytical model of a non-equal-size Halbach array was established based on the equivalent magnetic charge method and the field strength superposition principle. Comparisons were conducted between numerical simulations and analytical results of the proposed model. The relationship between the magnetic flux density at the air gap and the size parameters of the Halbach array was analyzed by means of a finite element calculation. The mirror image method was adopted to consider the influence of the ferromagnetic boundary on the magnetic flux density. Finally, a parametric model of the non-equal-size Halbach actuator was established, and the multi-objective optimization design was carried out using a genetic algorithm. The actuator with optimized parameters was manufactured and experiments were conducted to verify the proposed analytical model. The difference between the experimental results and the analytical results is only 5%, which verifies the correctness of the magnetic field analytical model of the non-equal-size Halbach actuator.
The maglev vibration isolation system exhibits excellent micro-vibration isolation performance (0.01 Hz to 100 Hz band) in the space environment. However, a collision between the base and the floating platform may occur in an ultra-low frequency range (≤0.01 Hz). To avoid collision, the relative position and attitude between the base and the floating platform needs to be accurately tracked and controlled. In this study, a novel measurement method with four groups of two-dimensional position-sensitive detectors equipped with four laser light sources was proposed. A high-precision relative position and attitude measurement model was established based on the geometric relationship of space coordinates. A proportional-differential (PD) fixed-point control algorithm was adopted to realize tracking control. The control performance of the system was evaluated through simulation. Experiments were also carried out to verify the stability of the system and the precision of the control algorithm. A maglev vibration isolation system prototype was constructed and a test system was established. The proposed relative position and attitude measurement model was verified and the six degrees of freedom relative position and attitude response of the system was tested. Based on the measurement model, the tracking control of the system was proven to have high precision.
The environment in space provides favorable conditions for space missions. However, low frequency vibration poses a great challenge to high sensitivity equipment, resulting in performance degradation of sensitive systems. Due to the ever-increasing requirements to protect sensitive payloads, there is a pressing need for micro-vibration suppression. This paper deals with the modeling and control of a maglev vibration isolation system. A high-precision nonlinear dynamic model with six degrees of freedom was derived, which contains the mathematical model of Lorentz actuators and umbilical cables. Regarding the system performance, a double closed-loop control strategy was proposed, and a sliding mode control algorithm was adopted to improve the vibration isolation performance. A simulation program of the system was developed in a MATLAB environment. A vibration isolation performance in the frequency range of 0.01–100 Hz and a tracking performance below 0.01 Hz were obtained. In order to verify the nonlinear dynamic model and the isolation performance, a principle prototype of the maglev isolation system equipped with accelerometers and position sensors was developed for the experiments. By comparing the simulation results and the experiment results, the nonlinear dynamic model of the maglev vibration isolation system was verified and the control strategy of the system was proved to be highly effective.
This paper presents an investigation on the feedback controller design for active noise control headphones under the condition that the frequency responses of the primary and secondary paths corresponding to the feedback microphone do not match to the ones corresponding to the human ear. The influence of such mismatches on the performance are analyzed first, and then an optimization method is proposed to enhance the comprehensive performance at the human ear. In the proposed method, the feedback loop is constructed directly with the feedback microphone and any extra filters of the virtual sensing techniques are avoided. Cascade biquad filters are used as the controller, which is in accordance with current applications. A differential evolution algorithm was used to solve the proposed optimization problem, and the optimal parameters of the controller were found. It has been shown by the experimental results that, at the dummy head ear position, good noise reduction performance could be obtained at the low frequency band with limited noise enhancement for high frequencies, even if large frequency response mismatches exist.
The maglev inertial actuators with high power and mass maybe effective for lateral vibration control of a propulsion shafting. But the mass power ratio of the actuators currently in use is too small to meet the requirements. In the paper, a maglev inertial actuator was innovatively designed with high mass power ratio. The structure of the magnetic circuit assembly and the suspending assembly were designed and optimized. To verify the property of the proposed maglev inertial actuator, a prototype with mass less than 8 kg was developed and tests were carried out. The minimum effective output force can reach 200 N within the frequency band of 20–300 Hz. A lateral vibration of a propulsion shafting system was constructed and the active control effect was tested. The experimental results show that the proposed maglev inertial actuator has a good effect on lateral vibration control of shafting.