The purpose of this paper was to evaluate the quality of bee honey from different sources: beekeeper, local market and organic honey. Sensory analysis was performed and the water content, pH, acidity, protein content and total metal content (Cu, Cr, Mn, Co, Ni, Pb, Cd, Fe) were determined. The sensory analysis was carried out by a group of untrained panelists for quality assessment of honey. The metal content was determined by graphite atomic absorption spectrometry (GTAAS). Mineralization was carried out in a microwave digestion system, in a high-pressure polytetrafluoroethylene (PTFE) vessel, using a standard acid-digestion protocol. The results regarding the physico-chemical parameters showed that the honey samples were in accordance with the quality regulations for honey as a commercial product. The concentration of metals in the investigated honey samples varied in the order Cu > Cr > Pb > Fe > Ni > Mn > Co > Cd, the values being within the limits established by the EU Commission (No. 1881/2006). The variations observed in the evaluated parameters can be caused by the difference in plant species from which the honey comes, the harvesting period and the level of environmental pollutants. The Pearson correlations between the physico-chemical parameters and the metals indicate that water content (w_c) is strongly negatively correlated with Cd and Ni, while pH is strongly positively correlated with Mn and Fe. Moreover, EC is strongly negatively correlated with Ni and Fe, and the Brix degrees are strongly positively correlated with Cd and Ni. Statistically significant positive correlation was found between Brix–Cd, Ni–Cd and Cu–Cr and a statistically significant negative correlation was detected between w_c and Cd.

The purpose of this work was to assess the levels of polycyclic aromatic hydrocarbons (PAHs) in some mollusks and fish species, collected during the summer of 2016–2018, from three sites representing the southern, middle, and northern areas of the Romanian Black Sea coast. The PAHs concentrations were determined from the edible tissues of some important seafood (Rapana venosa and Mytilus galloprovincialis mollusk species; Sprattus sprattus, Engraulis encrasicolus, and Trachurus mediterraneus ponticus pelagic fish species and Neogobius cephalarges benthic fish species). The PAHs were analyzed using gas chromatography-mass spectrometry. The average concentrations of these PAHs ranged from below detection limit of 0.0001 to 103.09 ± 11.18 µg/kg wet wt. in mollusk species, from 0.0001 to 147.45 ± 9.28 µg/kg wet wt. in pelagic fish species and from 0.0001 to 45.73 ± 5.28 µg/kg in benthic fish species. Among the two mollusks species, Rapana venosa accumulated significantly higher concentrations (p < 0.05) of PAHs, while among fish species, Trachurus mediterraneus ponticus accumulated significantly higher concentrations (p < 0.05) of total PAHs. Total PAH concentrations varied between the sites; the main presence of PAHs was observed in site 2 (middle location), the major contribution being given by the presence of phenanthrene (Ph), anthracene (An), and naphthalene (Na). PAHs contents in organisms varied according to the different species, their location in the water, their feeding habits (pelagic and benthic organisms) and differences in the quantification of LMW and HMW PAHs. PAH distribution patterns in pelagic and mollusk species are characterized by the abundance of LMW-PAHs. Most of the PAHs had a petrogenic origin, which indicates that the anthropogenic activities influenced PAH concentrations. Apart from Neogobius cephalarges species, the benzo[a]pyrene concentrations, measured in mollusks and fish species did not exceed the EU recommended limit.

This study presents the content of polycyclic aromatic hydrocarbons (PAHs), determined in 19 types of herbal tea sold in Romania. The instrumental analysis was performed using gas chromatography coupled with mass spectrometry (GC–MS). PAH distribution patterns are characterized by the presence of both low molecular weight (LMW), given especially by the presence of anthracene (An), and high molecular weight (HMW) compounds represented by benzo[a]pyrene (BaP). Among PAHs, 3-4 rings compounds were predominant in the analyzed samples. A statistical analysis was performed to assess the differences between the most PAHs in the 19 samples of herbal tea. Significant statistical difference was found between (An) group, on one hand, and (BaP), dibenz[a,h]anthracene (DahA) and indeno[1,2,3cd]pyrene (IP) groups, on the other hand. Results of diagnostic ratios showed that the main of PAHs in the herbal teas might be attributed to petrogenic (liquid fuels spills), pyrolytic (combustion of fuels) and coal sources. Taking into account the limits established by the European Communities Regulation no. 1933/2015 for both BaP and the sum of 4PAHs, in this study, one sample exceeded the value proposed for Σ4PAHs and five were higher than the limit value of BaP.

Using two methods (ferric reducing antioxidant power and radical scavenging activity), the total polyphenol content (Folin–Ciocalteu reagent) and polyphenol patterns (HPLC) in 10 commercial lager beer brands produced in Romania was determined. Samples bottled in glass, plastic and aluminium packages were analysed for each brand when available. Results have indicated considerable variations in the total and individual phenolic contents as well as antioxidant activity across beer brands. Gallic and feulic acids were the dominant phenolic compounds identified samples. The statistical analysis indicates a significant difference between the levels of antioxidant activity detected using DPPH and FRAP, for all three types of material considered. The statistical test ANOVA indicates that the polyphenol concentration is similar across all types of material.