We report a ductile $\beta$-type titanium alloy with body-centered cubic (bcc) crystal structure having a low Poisson’s ratio of 0.14. The almost identical ultralow bulk and shear moduli of $\sim 24\mathrm{GPa}$ combined with an ultrahigh strength of $\sim 0.9\mathrm{GPa}$ contribute to easy crystal distortion due to much-weakened chemical bonding of atoms in the crystal, leading to significant elastic softening in tension and elastic hardening in compression. The peculiar elastic and plastic deformation behaviors of the alloy are interpreted as a result of approaching the elastic limit of the bcc crystal under applied stress.

Ti-Nb-based Gum Metals exhibit extraordinary superelasticity with ultralow elastic modulus, superior strength and ductility and a peculiar dislocation-free deformation behavior, most of which challenge existing theories of crystal strength. Additionally, this kind of alloys actually displays even more anomalous mechanical properties, such as the non-linear superelastic behavior, accompanied by a pronounced tension-to-compression asymmetry and large ductility with a low Poisson's ratio. Two main contradictory arguments exist concerning the deformation mechanisms of those alloys, i.e., formation of reversible nanodisturbance and reversible martensitic transformation. Herein we used the in-situ synchrotron high-energy X-ray scattering technique to reveal the novel intrinsic physical origin of all anomalous mechanical properties of the Ti-24Nb-4Zr-8Sn-0.10O alloy, a typical gum-like metal. Our experiments provide direct evidence on two different kinds of interesting, stress-induced, reversible nanoscale martensitic transitions, i.e., the austenitic regions with B2 structure transform to α″ martensite and those with BCC structure transform to δ martensite.

Molybdenum disulfide has broad applications in catalysis, optoelectronics, and solid lubrication, where lanthanide (Ln) doping can be used to tune its physicochemical properties. The reduction of oxygen is an electrochemical process important in determining fuel cell efficiency, or a possible environmental-degradation mechanism for nanodevices and coatings consisting of Ln-doped MoS₂. Here, by combining density-functional theory calculations and current-potential polarization curve simulations, we show that the dopant-induced high oxygen reduction activity at Ln-MoS₂/water interfaces scales as a biperiodic function of Ln type. A defect-state pairing mechanism, which selectively stabilizes the hydroxyl and hydroperoxyl adsorbates on Ln-MoS₂, is proposed for the activity enhancement, and the biperiodic chemical trend in activity is found originating from the similar trends in intraatomic 4f–5d6s orbital hybridization and interatomic Ln–S bonding. A generic orbital-chemistry mechanism is described for explaining the simultaneous biperiodic trends observed in many electronic, thermodynamic, and kinetic properties.