Bismuth vanadate (BiVO₄) is one of the best bismuth-based semiconducting materials because of its narrow band gap energy, good visible light absorption, unique physical and chemical characteristics, and non-toxic nature. In addition, BiVO₄ with different morphologies has been synthesized and exhibited excellent visible light photocatalytic efficiency in the degradation of various organic pollutants, including volatile organic compounds (VOCs). Nevertheless, the commercial scale utilization of BiVO₄ is significantly limited because of the poor separation (faster recombination rate) and transport ability of photogenerated electron–hole pairs. So, engineering/modifications of BiVO₄ materials are performed to enhance their structural, electronic, and morphological properties. Thus, this review article aims to provide a critical overview of advanced oxidation processes (AOPs), various semiconducting nanomaterials, BiVO₄ synthesis methodologies, engineering of BiVO₄ properties through making binary and ternary nanocomposites, and coupling with metals/non-metals and metal nanoparticles and the development of Z-scheme type nanocomposites, etc., and their visible light photocatalytic efficiency in VOCs degradation. In addition, future challenges and the way forward for improving the commercial-scale application of BiVO₄-based semiconducting nanomaterials are also discussed. Thus, we hope that this review is a valuable resource for designing BiVO₄-based nanocomposites with superior visible-light-driven photocatalytic efficiency in VOCs degradation.

A schematic illustration of PANI–MnMoO₄synthesis for overall water splitting is demonstrated with excellent electrocatalytic activity and stability.

A feasible solution-processed surface modification is presented to boost the intrinsic photoactivity of BiVO₄via hydrothermal, solvothermal and solid-state reactions, enabling as a promising photocatalyst for degradation of dye pollutants in water.

The photocatalytic removal of water contaminants for ecological systems has become essential in the past few decades. Consequently, for commercialization, cost-efficient, earth-abundant and easy to synthesize photocatalysts for dye degradation are of urgent need. We have demonstrated a simple and feasible approach for fabricating TiO₂–SnO₂ nanocomposite photocatalysts via urea-assisted-thermal-decomposition with different mass ratios. The as-synthesized materials were characterized by different physicochemical techniques. The phase formation and crystallite size were calculated by using XRD. The STEM, UV-Vis, DRS, HR-TEM and EDS revealed the effective formation of the heterojunction between TiO₂ and SnO₂, and enrichment in the UV-absorption spectrum. All synthesized materials were used for the photocatalytic degradation of methyl orange (MO) under UV light. The optimized results of the TiO₂–SnO₂ nanocomposite showed excellent photostability and photocatalytic activity over a number of degradation-reaction cycles of methyl-orange (MO) dye under the illumination of ultraviolet light. In addition, the recent method has great potential to be applied as a proficient method for mixed-metal-oxide-nanocomposite synthesis.

An easy and cost-effective route is demonstrated to grow spongy-network-like polyaniline (SpN-PANI) thin films on stainless steel (SS) by galvanostatic electrodeposition. Through X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, and scanning electron microscopy (SEM) characterizations, the physicochemical properties of the SpN-PANI thin films were fine-tuned for supercapacitor application. The hydrophilic nature of SpN-PANI thin films was examined by using contact angle measurements. Next, the capacitive behavior of the SpN-PANI thin film was assessed by using cyclic voltammetry (CV), galvanostatic charging-discharging (GCD), and electrochemical impedance spectroscopy (EIS). Specifically, these results show that SpN-PANI thin films can exhibit a maximum specific capacitance of 580 F.g⁻¹ at a scan rate of 5 mV.s⁻¹ in a 0.5 M Na₂SO₄ electrolyte solution, as well as superior cycling stability (84% capacity retention after 1000 cycles). Thus, the strategy presented here can be applicable to produce a SpN-PANI-based thin film which has prospects as an active electrode material for supercapacitor devices.

Synergistic heterostructure engineering of NH₄NiPO₄·H₂O and CdIn₂S₄/Ni₃S₂ for boosting urea oxidation reaction performance.