There are a number of gas ionization sensors using carbon nanotubes as cathode or anode. Unfortunately, their applications are greatly limited by their multi-valued sensitivity, one output value corresponding to several measured concentration values. Here we describe a triple-electrode structure featuring two electric fields with opposite directions, which enable us to overcome the multi-valued sensitivity problem at 1 atm in a wide range of gas concentrations. We used a carbon nanotube array as the first electrode, and the two electric fields between the upper and the lower interelectrode gaps were designed to extract positive ions generated in the upper gap, hence significantly reduced positive ion bombardment on the nanotube electrode, which allowed us to maintain a high electric field near the nanotube tips, leading to a single-valued sensitivity and a long nanotube life. We have demonstrated detection of various gases and simultaneously monitoring temperature, and a potential for applications.
The existing temperature sensors using carbon nanotubes (CNTs) are limited by low sensitivity, complicated processes, or dependence on microscopy to observe the experimental results. Here we report the fabrication and successful testing of an ionization temperature sensor featuring non-self-sustaining discharge. The sharp tips of nanotubes generate high electric fields at relatively low voltages, lowering the work function of electrons emitted by CNTs, and thereby enabling the safe operation of such sensors. Due to the temperature effect on the electron emission of CNTs, the collecting current exhibited an exponential increase with temperature rising from 20 °C to 100 °C. Additionally, a higher temperature coefficient of 0.04 K−1 was obtained at 24 V voltage applied on the extracting electrode, higher than the values of other reported CNT-based temperature sensors. The triple-electrode ionization temperature sensor is easy to fabricate and converts the temperature change directly into an electrical signal. It shows a high temperature coefficient and good application potential.
2 February 2021 in IEEE Transactions on Industrial Electronics
On-line detection of fault characteristic gases released by the insulation oil of transformers is developed as a scientific basis for estimating explosion accidents. However, the performance of most gas sensors, such as H 2 and C 2 H 2 sensors, is usually affected by temperature, and there exists large detection error when the temperature of transformer oil changes in operation. And the existing temperature compensation methods suffer from problems such as low integration, large volume, and high costs. Herein, a sensor array based on three triple-electrode sensors with carbon nanotubes was fabricated. Each of the three sensors has three vertically stacked electrodes with various interelectrode distances. The first and second sensors were used to detect H 2 and C 2 H 2 , respectively, and the third sensor was used to measure temperature. All the detection mechanisms are based on the dependence of discharge current on gas concentration and temperature. The sensor array could detect H 2 /C 2 H 2 mixture and temperature due to the exponential function between the output currents and electrode separations. The proposed sensor exhibited low relative and repeatability error values less than 5.1% and 4.9%, respectively, and displayed humidity compensation potential like temperature. High integration makes the sensor array superior among the other mechanism sensors.
A miniaturized reliability test system for microdevices with controlled environmental parameters is presented. The system is capable of measuring key electrical parameters of the microdevices while controlling the environmental conditions around the microdevices. The test system is compact and thus can be integrated with standard test equipment for microdevices. By using a feed-forward decoupling algorithm, the presented test system is capable of generating a temperature range of 0–120 °C and a humidity range of 20–90% RH (0–55 °C), within a small footprint and weight. The accuracy for temperature and humidity control is ±0.1 °C and ±1% RH (30 °C), respectively. The functionality of the proposed test system is verified by integrating it with a piezo shaker to test the environmental reliability of an electromagnetic vibration energy harvester. The proposed system can be used as a proof-of-technology platform for characterizing the performance of microdevices with controlled environmental parameters.
7 December 2020 in IEEE Transactions on Electron Devices
Surface treatment is quite vital to reduce the reverse leakage current and improve the current On-Off ratio of gallium nitride (GaN) quasi-vertical Schottky barrier diode (SBD). In this work, we report a new nondestructive low temperature supercritical CO₂ fluid (SCF) nitridation technology to treat the surface of GaN and substantially reduce the leakage current of GaN quasi-vertical SBD. The X-ray photoelectron spectroscopy (XPS) reveals the increased nitriding degree and oxygen doping degree in the form of GaOₓ after the SCF process results in the leakage performance improvement. As a result, the defects at metal/semiconductor interface are passivated. Also, because of NH-₂ and OH⁻ generated from the SCF process, the surface peak electric field of n⁻GaN decreases, and thus the breakdown voltage is enhanced. The reverse leakage current density is reduced by more than three orders of magnitude from 3.7 x 10⁻⁶ to 3.52 x 10⁻⁹ A/cm² (at -3 V) and the ON-/OFF-current ratio is improved by three orders from 8 x 10⁷ to 5.74 x 10¹⁰.
Ionized gas sensors using nano materials show good sensitivity to gases. Therefore, the nano material structure has a great impact on the performance of sensors. However, the current researches have mainly focused on the influence of nanostructure on field enhancement factors without considering the gas discharge process in space. Therefore, these methods are not suitable for the research of ionized gas sensors. In this paper, a fluid model is established based on the principle of gas discharge. It consists with mass conservation equation, energy conservation equation, and Poisson equation. The influence of electrode separation, screening effects and nanostructure on the cathode current density was analyzed compared with the field enhancement factor. We not only discussed the influence of nanomaterial morphology, but also considered the influence of nanomaterial quantity on gas discharge, which made the research results somewhat different from the previous ones. The experimental results show that the simulation results obtained by the established model can correctly reflect the discharge characteristics of the ionized gas sensor. The methods and results presented in this paper are expected to be applied to the design of device based on gas discharge.