In order to provide a comfortable living and working environment indoors in tropical countries, the outdoor air often needs to be cooled and dehumidified before it enters the rooms. Membrane separation is an emerging technology for air dehumidification and it is based on the solution diffusion mechanism. Water molecules are preferentially permeating through the membranes due to its smaller kinetic diameter and higher condensability than the other gases. Compared to other dehumidification technologies such as direct cooling or desiccation, there is no phase transition involved in membrane dehumidification, neither the contact between the fresh air stream and the desiccants. Hence, membrane dehumidification would not only require less energy consumption but also avoid cross-contamination problems. A pilot scale air dehumidification system is built in this study which comprises nine pieces of one-inch PAN/PDMS hollow fiber membrane modules. A 150 h long-term test shows that the membrane modules has good water vapor transport properties by using a low vacuum force of only 0.78 bar absolute pressure at the lumen side. The water vapor concentration of the feed humid air decreases dramatically from a range of 18–22 g/m³ to a range of 13.5–18.3 g/m³. Most importantly, the total energy saving is up to 26.2% compared with the conventional air conditioning process.

Although various polymer membrane materials have been applied to gas separation, there is a trade-off relationship between permeability and selectivity, limiting their wider applications. In this paper, the relationship between the gas permeation behavior of polyphenylsulfone(PPSU)-based materials and their chemical structure for gas separation has been systematically investigated. A PPSU homopolymer and three kinds of 3,3′,5,5′-tetramethyl-4,4′-biphenol (TMBP)-based polyphenylsulfone (TMPPSf) copolymers were synthesized by controlling the TMBP content. As the TMPPSf content increases, the inter-molecular chain distance (or d-spacing value) increases. Data from positron annihilation life-time spectroscopy (PALS) indicate the copolymer with a higher TMPPSf content has a larger fractional free volume (FFV). The logarithm of their O₂, N₂, CO₂, and CH₄ permeability was found to increase linearly with an increase in TMPPSf content but decrease linearly with increasing 1/FFV. The enhanced permeability results from the increases in both sorption coefficient and gas diffusivity of copolymers. Interestingly, the gas permeability increases while the selectivity stays stable due to the presence of methyl groups in TMPPSf, which not only increases the free volume but also rigidifies the polymer chains. This study may provide a new strategy to break the trade-off law and increase the permeability of polymer materials largely.

Currently, cellulose acetate (CA) membranes dominate membrane-based CO₂ separation for natural gas purification due to their economical and green nature. However, their lower CO₂ permeability and ease of plasticization are the drawbacks. To overcome these weaknesses, we have developed high-performance mixed matrix membranes (MMMs) consisting of cellulose triacetate (CTA), cellulose diacetate (CDA), and amine functionalized zeolitic imidazolate frameworks (NH₂-ZIF-8) for CO₂ separation. The NH₂-ZIF-8 was chosen as a filler because (1) its pore size is between the kinetic diameters of CO₂ and CH₄ and (2) the NH₂ groups attached on the surface of NH₂-ZIF-8 have good affinity with CO₂ molecules. The incorporation of NH₂-ZIF-8 in the CTA/CDA blend matrix improved both the gas separation performance and plasticization resistance. The optimized membrane containing 15 wt.% of NH₂-ZIF-8 had a CO₂ permeability of 11.33 Barrer at 35 °C under the trans-membrane pressure of 5 bar. This is 2-fold higher than the pristine membrane, while showing a superior CO₂/CH₄ selectivity of 33. In addition, the former had 106% higher CO₂ plasticization resistance of up to about 21 bar and an impressive mixed gas CO₂/CH₄ selectivity of about 40. Therefore, the newly fabricated MMMs based on the CTA/CDA blend may have great potential for CO₂ separation in the natural gas industry.