Herein, we report novel catalytic methodologies for protodecarboxylations and decarboxylative deuterations of carboxylic acids utilizing a silver-containing hybrid material as a heterogeneous noble metal catalyst. After an initial batch method development, a chemically intensified continuous flow process was established in a simple packed-bed system which enabled gram-scale protodecarboxlyations without detectable structural degradation of the catalyst. The scope and applicability of the batch and flow processes were demonstrated through decarboxylations of a diverse set of aromatic carboxylic acids. Catalytic decarboxylative deuterations were achieved on the basis of the reaction conditions developed for the protodecarboxylations using D₂O as a readily available deuterium source.

In hydrometallurgical processing and acidic wastewater treatment, one of the neutralizing agents employed is MgO or Mg(OH)₂. At the end of this process, the resulting solution, which is rich in SO₄²⁻ and Mg²⁺ is treated with lime to remove (or minimize the amount) of these ions via the precipitation of Mg(OH)₂ and CaSO₄·2H₂O (gypsum). In our work, an attempt was made to separate the two solids by increasing the induction time of the gypsum precipitation, thus regenerating relatively pure Mg(OH)₂ which could be reused in wastewater treatments or hydrometallurgical processing circuits, and in this way, significantly enhancing the economic viability of the process. During our experiments, the reaction of an MgSO₄ solution with milk of lime prepared from quicklime was studied. The effects of a range of organic additives, which can slow down the precipitation of gypsum have been assessed. The process was optimized for the most promising inhibiting agent—that is, the citrate ion. The reactions were continuously monitored in situ by conductometric measurements with parallel monitoring of solution pH and temperature. ICP-OES measurements were also carried out on samples taken from the reaction slurry. The composition of the precipitating solids at different reaction times was established by powder XRD and their morphology by SEM. Finally, experiments were carried out to locate the additive after the completion of the precipitation reaction to get information about its potential reuse.

Anionic surfactants, such as sodium linear alkylbenzene sulfonates (NaLAS), are utilized in various fields, including industry, household, and agriculture. The efficiency of their use in aqueous environments is significantly affected by the presence of cations, Ca²⁺ and Mg²⁺ in particular, as they can decrease the concentration of the surfactant due to precipitation. To understand cation–sulfonate interactions better, we study both NaLAS colloidal solutions in the presence of CaCl₂ and precipitates forming at higher salt concentrations. Upon addition of CaCl₂, we find the surface tension and critical micelle concentration of NaLAS to decrease significantly, in line with earlier findings for alkylbenzylsulfonates in the presence of divalent cations. Strikingly, an increase in the surface tension is discernible above 0.6 g L^–1 NaLAS, accompanied by the decrease of apparent micelle sizes, which in turn gives rise to transparent systems. Thus, there appears to be a second critical concentration indicating another micellar equilibrium. Furthermore, the maximum salt tolerance of the surfactant is 0.1 g L^–1 Ca²⁺, above which rapid precipitation occurs yielding sparingly soluble CaLAS₂∙2H₂O.

The synthesis of the copper-poor and aluminum-rich layered double hydroxides (LDHs) of the CuAl₄ type was optimized in detail in this work, by applying an intense mechanochemical treatment to activate the gibbsite starting reagent. The phase-pure forms of these LDHs were prepared for the first time; using copper nitrate and perchlorate salts during the syntheses turned out to be the key to avoiding the formation of copper hydroxide sideproducts. Based on the use of the optimized syntheses parameters, the preparation of layered triple and multiple hydroxides was also attempted using Ni(II), Co(II), Zn(II) and even Mg(II) ions. These studies let us identify the relative positions of the incorporating cations in the well-known selectivity series as Ni²⁺ >> Cu²⁺ >> Zn²⁺ > Co²⁺ >> Mg²⁺. The solids formed were characterized by using powder X-ray diffractometry, UV–Vis diffuse reflectance spectroscopy, Fourier-transform infrared spectroscopy, thermogravimetric analysis and scanning electron microscopy. The catalytic potential of the samples was investigated in carbon monoxide oxidation reactions at atmospheric pressure, supported by an in situ diffuse reflectance infrared spectroscopy probe. All solids proved to be active and the combination of the nickel and cobalt incorporation (which resulted in a NiCoAl₈ layered triple hydroxide) brought outstanding benefits regarding low-temperature oxidation and increased carbon monoxide conversion values.