Styrene-butadiene-styrene (SBS) is widely used in asphalt modification to obtain superior high-temperature performance. Nevertheless, studies on the low-temperature properties of SBS-modified asphalt are not satisfactory. Orthogonal tests are valid in analysing the results. In this paper, the main factors (SBS content, sulfur content, and the addition of rubber processing oil) for improving the low-temperature performance of SBS-modified asphalt were analyzed base on the orthogonal tests. Firstly, the frequency sweep test, bending beam rheometer (BBR) test, and force-ductility test were conducted to evaluate the low-temperature properties of SBS-modified asphalt. Investigation of low-temperature parameters obtained through these tests was conducted base on the orthogonal analysis method. The G-R parameter was abandoned in the analysis of the orthogonal method for the result that the increase of SBS content was negative to the low-temperature properties by the Glover-Rowe (G-R) parameter, which were contrary to the results of BBR and force-ductility tests. Moreover, the other parameters (ΔT_c and toughness) sorted according to the orthogonal analysis method indicated the effect on low-temperature performance of the SBS-modified asphalt as SBS content > rubber processing oil > sulfur. As shown above that both SBS and rubber processing oil play a critical role in improving the low-temperature properties of SBS-modified asphalt, for SBS could resist the generation and subsequent propagation of cracks while the rubber processing oil could supplement the maltene loss.

The long-term effect of climate factors, such as sunlight, oxygen, and water, leads to the performance degradation of the asphalt mastic, which is the binding part in the asphalt mixture. It is not conducive to satisfy the long-term performance requirements of long-life asphalt pavement. In this study, five kinds of base asphalt mastic and styrene-butadiene-styrene (SBS) modified asphalt mastic were prepared with the filler-asphalt ratio of 0.6, 0.8, 1.0, 1.2, and 1.4. The indoor simulated weather aging tests were carried out considering multi-factors including sunlight, oxygen, and water. The master curves of the complex shear modulus and phase angle of the asphalt mastic with different aging degrees were obtained by the frequency sweep test. The curves of fatigue damage characteristics and fatigue life were fitted based on the viscoelastic continuum damage (VECD) model. The influence of weather aging on the viscoelasticity and fatigue performance of asphalt mastic were analyzed. Results indicated that the effect of weather aging increases the elastic component and decreases the viscous component. The fatigue performance of SBS modified asphalt mastic was better than that of base asphalt mastic. As the aging degree deepens, the brittle failure characteristics of asphalt mastic with a higher filler–asphalt ratio were more obvious. The base asphalt mastic becomes more sensitive to the strain level due to weather aging, and its fatigue life increased under the low strain loading and decreased under the high strain loading. The fatigue performance of SBS modified asphalt mastic was less sensitive to the strain level. The fatigue life reduced after aging under low and high strain load. Taking the impact of weather aging on the fatigue performance into consideration, the optimal filler–asphalt ratios of the base asphalt mastic SBS modified asphalt mastic are 1.0 and 1.2, respectively.

The performance of Styrene-butadiene-styrene (SBS) modified asphalt is closely related to the content of SBS modifier. In the production process of modified asphalt, a certain amount of additive such as sulfur and rubber oil may be added to reduce the segregation and promote the swelling of the polymer, but the effect of these additives on determining SBS content in asphalt is not yet clear. This paper presents the calibration curves of SBS content based on rutting factor and creep slope and points out its defects according to the temperature scanning test and the bending beam rheometer test. Subsequently, using Fourier transform infrared spectroscopy (FTIR) for rapid determination of polymer content in SBS modified asphalt based on orthogonal test and then the effects of additives such as asphalt type, SBS content, rubber oil and sulfur on the accuracy of polymer content determination by FTIR were investigated. Moreover, in the orthogonal tests of adding sulfur and rubber oil, the multivariate analysis of variance (MANOVA) was firstly used to analyze the additives influence on the test accuracy of FITR. Results indicated that the influencing degree of different additives is different. The influence of sulfur on the determination accuracy is greater than that of rubber oil. Therefore, the rapid determination method needs further improvement.

The residue of emulsified asphalt is its final state when it becomes part of an asphalt mixture. Therefore, the mechanical properties of the residue have a significant impact on the performance of emulsified asphalt mixtures. Dynamic shear rheological tests and fluorescence microscopy were conducted to explore the effects of emulsification and aging on the rheological properties and micro-morphology of emulsified asphalt residue. The results of both the temperature sweep and multiple stress creep recovery tests indicated that the emulsification of the asphalt had different effects on the rheological properties of the base asphalt and the styrene-butadiene-styrene (SBS)-modified asphalt. For the base asphalt, emulsification increases the complex shear modulus by about 5% and reduces irrecoverable creep flexibility by 30%. However, the physical grinding effect of the colloid mill during the emulsification process could destroy the internal spatial network structure of SBS, leading to a reduction in the complex shear modulus by about 5% and a 10% increase in irrecoverable creep flexibility. This phenomenon is similar to the aging of SBS-modified asphalt, which, in turn, leads to a decline in the performance of emulsified SBS-modified asphalt residues.