The influence of alloying element Mg on Na and Sr modifying Al-7Si hypoeutectic alloys was investigated. The residual content of Na and the morphology of modified eutectic silicon were characterized. It was found that the alloying element Mg had an enhanced effect on the uptake of sodium in the Al-7Si hypoeutectic alloy modified by the Na-contained modifier. Moreover, the morphology of eutectic silicon of the modified Al-7Si alloys was significantly different from that of Al-7Si-0.4Mg alloys in the present research. When the addition of the modifier is enough, both modifiers could entirely modify the eutectic silicon phase of Al-7Si alloys, while incompletely modified eutectic silicon was observed in both Na-modified and Sr-modified Al-7Si-0.4Mg alloy. It was observed that there was an adhering relationship between the partially modified eutectic silicon with Mg-rich phases. According to the results, it can be proposed that the addition of Mg will affect the solidification behavior of alloys, thereby, leading to the incomplete modification of eutectic silicon phases.
The modification of eutectic silicon plays a crucial role in enhancing the mechanical properties of hypoeutectic Al–Si alloys. However, there is still limited understanding regarding the factors that affect the modification of eutectic silicon in hypoeutectic Al–Si alloys, particularly in terms of the role played by alloying elements during the modification process. In order to address this gap, this study aimed to investigate the influence of two key alloying elements, Mg and Cu, on the modification effect of Sr. To achieve this, the morphology of eutectic silicon in the as-cast and heat-treated states of Al–7Si alloy, modified with Sr, was examined using scanning electron microscopy (SEM). Different levels of magnesium and copper content were used to analyze their impact on the modification effect of Sr. The results obtained from the analysis revealed that both Mg and Cu significantly weaken the modification effect of strontium on eutectic silicon. Furthermore, it was observed that the degree of deterioration in the modification effect increases progressively with higher alloying element content. Interestingly, increasing the strontium content and adjusting the cooling rate were found to be ineffective in eliminating this weakening effect caused by Mg and Cu. These findings highlight the complex interplay between alloying elements and the modification process of eutectic silicon in hypoeutectic Al–Si alloys. A deeper understanding of these factors is essential for the development of effective strategies to optimize the mechanical properties of such alloys.
The effect of annealing temperature on microstructure and mechanical properties of a cold-rolled Al–10Mg alloy has been investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), electron backscatter diffraction (EBSD) and tensile testing. The results showed that supersaturated Mg precipitated along grain boundaries and deformation bands during annealing treatment and precipitation size and the concentration of solid solution Mg atoms increased with the rising of annealing temperature. When annealed at low temperature, accumulation and annihilation of dislocations were the primary way of recovery; as temperature increased to 300 °C, recrystallized grains were formed around the large size β phase through particle-stimulated nucleation. A high ultimate strength (550 MPa) and a middle ductility (14%) were obtained when the Al–10Mg alloy was annealed at 200 °C for 1 h. The abnormal decrease of elongation when the Al–10Mg alloy was annealed at 250–300 °C was due to the formation of a continuous network distribution of large size β phase particles along grain boundaries.
The oxide film on the scrap surface is one of the primary sources of oxide inclusions in the aluminum melt. Understanding the evolution of the oxide films in the aluminum melt is an important step for developing efficient recycling technologies and controlling the quality of the product. In the present study, we studied the evolution behavior of the oxide film in the aluminum melt. The oxide films were introduced via aluminum alloy scraps into the melt, and the micro-morphology and composition of the oxide film were analyzed by scanning electron microscope and energy spectrum. Results show that the oxide film on the surface of 1235 alloy foil, A356 alloy turning, and 5083 alloy scalping were broken into small flake oxide film and then transformed into minor granular oxide when the scraps were charged into commercial purity aluminum melt. However, in aluminum alloy melt containing magnesium, the oxide film remained an intact sheet shape up to a certain melt dwelling time.
The inhibition of recrystallization in high-strain nickel-based single-crystal superalloys remains a critical challenge for advanced turbine blade applications. This study investigates the evolution of the primary γ’ phase and dislocation during annealing in a third-generation Re-containing single-crystal superalloy (WZ30) subjected to 5% compressive deformation. Isochronal annealing (700 to 1200 °C, 1 min) combined with scanning electron microscopy (SEM) and an electron backscatter diffraction (EBSD) analysis revealed a nonlinear variation of the geometrically necessary dislocation (GND) density, which reached a minimum of 1000 °C with 62.7% of the primary γ’ phase retained. Prolonged recovery annealing at 1000 °C for 10 h effectively inhibited recrystallization during subsequent solution heat treatment. This result provides a practical strategy for inhibiting recrystallization in single-crystal superalloys.
To get an insight into the residual sodium content of Al–Mg alloys, three types of sodium-containing fluxes were introduced into the melt with different magnesium content. The increment, existing form and distribution of sodium in Al–Mg alloys with different magnesium content were analyzed. The results show that the influence of different sodium salts on the increment of sodium in Al–10Mg alloy is significantly different. The NaF raised the sodium level in Al–10Mg alloy to the highest extent, Na3AlF6 coming second, and NaCl did not have an obvious influence. The magnesium element in the aluminum melt was found to be the key factor leading to the increment of sodium level. After the salt fluxing treatment of aluminum alloy with different magnesium content, this increment would be proportional to the content of magnesium. EDS mapping indicates the sodium introduced by the fluxes was distributed in the form of Na-rich particles in Al–Mg alloys and preferentially located near Al3Mg2(β) phase in the situation of high magnesium content.