Limited predictions of thin-film composite (TFC) membranes’ behavior and functional life exist due to the lack of accurate data on their mechanical behavior under different operational conditions. A comprehensive investigation of the mechanical behavior of TFC membranes addressing deformation and failure, temperature and strain rate sensitivity, and anisotropy is presented. Tensile tests were conducted on commercial membranes as well as on individual membrane layers prepared in our laboratories. The results reveal the overall mechanical strength of the membrane is provided by the polyester layer (bottom layer), while the rupture stress for the middle and top layers is at least 10 times smaller than that of the polyester layer. High anisotropic behavior was observed and is attributed to the nonwoven structure of the polyester layer. Rupture stress in the transverse (90°) direction was one-third of the rupture stress in the casting direction. Limited temperature and strain rate dependence was observed in the temperature range that exists during operation. Scanning electron microscopy images of the fractured surfaces were also analyzed and correlated with the mechanical behavior. The presented results provide new insights into the mechanical behavior of thin-film composite membranes and can be used to inform novel membrane designs and fabrication techniques.

In this study, we report on the corrosion behavior of hybrid steel/glass fiber-reinforced polymer (GFRP) composite pipes under harsh corrosive conditions for prolonged durations. Specimens were immersed in highly concentrated solutions of hydrochloric acid, sodium chloride, and sulfuric acid for durations up to one year. Detailed qualitative analysis using scanning electron microscopy (SEM), X-ray diffraction analysis (XRD), and energy-dispersive X-ray spectroscopy (EDX) is presented. It is shown that the hybrid pipes have excellent corrosion resistance with a corrosion rate of less than 1% of the corrosion rate for conventional steel pipes. That low corrosion rate can be attributed to the formation of pores in the GFRP layer due to increased absorption and saturation moisture in the material with increased soaking time. This can be reduced or even prevented through a more controlled process for fabricating the protective layers. These promising results call for more utilization of GFRP protective layers in novel design concepts to control corrosion.

Corrosion remains one of the major and most costly challenges faced by the steel industry. Various fiber-reinforced polymer coating systems have been proposed to protect metallic piping distribution networks against corrosion. Despite increasing interest among scientific and industrial communities, there is only limited predictive capability for selecting the optimum composite system for a given corrosive condition. In this study, we present a comprehensive evaluation of the electrochemical behavior of two different fiber-reinforced polymer composite systems against the corrosion of carbon steel pipes under a wide range of acidic and corrosive solutions. The composites were made of glass and Kevlar fibers with an epoxy resin matrix and were subjected to corrosive solutions of 0.5 M NaCl, 0.5 M HCl, and 0.5 M H₂SO₄. The kinetics of the corrosion reactions were evaluated using potentiodynamic polarization (PDP) tests. In addition, electrochemical impedance spectroscopy (EIS) tests were carried out at open circuit potentials (OCPs). It was demonstrated that the glass fiber-reinforced polymer coating system offered the best protection against corrosion, with a high stability against deterioration when compared with epoxy and Kevlar fiber-reinforced polymer coating systems. Scanning electron microscopy images revealed cracks and deteriorated embedded fibers due to acid attack, sustained/assisted by the diffusion of the corrosion species.